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Metalloporphyrin-based supramolecular catalysts
Yang Zaiwen1,3; Yang Jin2; Huang Xiaojuan1; Tang Ning2; Wu Biao1
刊名Progress in chemistry
2009-04-01
卷号21期号:4页码:588-599
关键词Supramolecular chemistry Catalysis Metalloporphyrins Enzyme mimicking Recognition
ISSN号1005-281X
通讯作者Yang zaiwen()
英文摘要Metalloporphyrin-based supramolecular catalyst is one of the most important research subjects in supramolecular catalysis. supramolecular micro-reactors containing the metalloporphyrin backbone provide a specific micro-environment for the active sites in catalytic processes, which can greatly improve the selectivities and catalytic efficiencies of the catalysts. this review presents the recent progress in the design, structures and catalytic properties of metalloporphyrins as supramolecular catalysts from the aspects of the construction of supramolecular catalyst precursors (based on cyclodextrin, template, etc.) and their catalytic applications (in mimicking cytochrome p450 enzymes, electrocatalysis, photocatalysis, etc.), as well as a perspective of the future development in this field.
WOS关键词CYCLODEXTRIN-SANDWICHED PORPHYRIN ; TRANSITION-METAL CATALYSTS ; EPOXIDATION CATALYSTS ; ARTIFICIAL CYTOCHROME-P-450 ; ELECTROCATALYTIC REDUCTION ; SUBSTRATE-SELECTIVITY ; MANGANESE PORPHYRINS ; MOLECULAR-OXYGEN ; ACETATE CLUSTERS ; COBALT PORPHYRIN
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者CHINESE ACAD SCIENCES
WOS记录号WOS:000265397200003
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2401779
专题中国科学院大学
通讯作者Yang Zaiwen
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Yang Zaiwen,Yang Jin,Huang Xiaojuan,et al. Metalloporphyrin-based supramolecular catalysts[J]. Progress in chemistry,2009,21(4):588-599.
APA Yang Zaiwen,Yang Jin,Huang Xiaojuan,Tang Ning,&Wu Biao.(2009).Metalloporphyrin-based supramolecular catalysts.Progress in chemistry,21(4),588-599.
MLA Yang Zaiwen,et al."Metalloporphyrin-based supramolecular catalysts".Progress in chemistry 21.4(2009):588-599.
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