Metalloporphyrin-based supramolecular catalysts | |
Yang Zaiwen1,3; Yang Jin2; Huang Xiaojuan1; Tang Ning2; Wu Biao1 | |
刊名 | Progress in chemistry |
2009-04-01 | |
卷号 | 21期号:4页码:588-599 |
关键词 | Supramolecular chemistry Catalysis Metalloporphyrins Enzyme mimicking Recognition |
ISSN号 | 1005-281X |
通讯作者 | Yang zaiwen() |
英文摘要 | Metalloporphyrin-based supramolecular catalyst is one of the most important research subjects in supramolecular catalysis. supramolecular micro-reactors containing the metalloporphyrin backbone provide a specific micro-environment for the active sites in catalytic processes, which can greatly improve the selectivities and catalytic efficiencies of the catalysts. this review presents the recent progress in the design, structures and catalytic properties of metalloporphyrins as supramolecular catalysts from the aspects of the construction of supramolecular catalyst precursors (based on cyclodextrin, template, etc.) and their catalytic applications (in mimicking cytochrome p450 enzymes, electrocatalysis, photocatalysis, etc.), as well as a perspective of the future development in this field. |
WOS关键词 | CYCLODEXTRIN-SANDWICHED PORPHYRIN ; TRANSITION-METAL CATALYSTS ; EPOXIDATION CATALYSTS ; ARTIFICIAL CYTOCHROME-P-450 ; ELECTROCATALYTIC REDUCTION ; SUBSTRATE-SELECTIVITY ; MANGANESE PORPHYRINS ; MOLECULAR-OXYGEN ; ACETATE CLUSTERS ; COBALT PORPHYRIN |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
出版者 | CHINESE ACAD SCIENCES |
WOS记录号 | WOS:000265397200003 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2401779 |
专题 | 中国科学院大学 |
通讯作者 | Yang Zaiwen |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Yang Zaiwen,Yang Jin,Huang Xiaojuan,et al. Metalloporphyrin-based supramolecular catalysts[J]. Progress in chemistry,2009,21(4):588-599. |
APA | Yang Zaiwen,Yang Jin,Huang Xiaojuan,Tang Ning,&Wu Biao.(2009).Metalloporphyrin-based supramolecular catalysts.Progress in chemistry,21(4),588-599. |
MLA | Yang Zaiwen,et al."Metalloporphyrin-based supramolecular catalysts".Progress in chemistry 21.4(2009):588-599. |
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