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From t2,2@bmmim to alkali@t2,2@bmmim ivory ball-like clusters: ionothermal syntheses, precise doping, and photocatalytic properties
Du, Cheng-Feng1,2; Li, Jian-Rong1; Zhang, Bo1,2; Shen, Nan-Nan1,2; Huang, Xiao-Ying1
刊名Inorganic chemistry
2015-06-15
卷号54期号:12页码:5874-5878
ISSN号0020-1669
DOI10.1021/acs.inorgchem.5b00652
通讯作者Li, jian-rong(jrli@fjirsm.ac.cn)
英文摘要Presented here are the syntheses, structures, and properties of an in-sn-se compound based on a ternary super-supertetrahedral t2,2 cluster nested by bmrnirn cations and two of its alkali-doped quaternary analogues. by means of a one-pot ionothermal method, an alkali metal ion (cs+ or rb+) could be precisely doped into the central cavity of the cluster, forming an alkali@t2,2@bmmim quaternary cluster. remarkably, the undoped compound exhibited excellent stability and visible light photodegradation ability over a wide range of ph, especially in acidic conditions.
WOS关键词VISIBLE-LIGHT ; IONIC LIQUIDS ; METHYL-ORANGE ; NANOCRYSTALS SYNTHESIS ; SHORT HISTORY ; DEGRADATION ; TIO2 ; NANOPARTICLES ; NANOMATERIALS ; NANOCLUSTER
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000356467100028
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2376394
专题中国科学院大学
通讯作者Li, Jian-Rong
作者单位1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Du, Cheng-Feng,Li, Jian-Rong,Zhang, Bo,et al. From t2,2@bmmim to alkali@t2,2@bmmim ivory ball-like clusters: ionothermal syntheses, precise doping, and photocatalytic properties[J]. Inorganic chemistry,2015,54(12):5874-5878.
APA Du, Cheng-Feng,Li, Jian-Rong,Zhang, Bo,Shen, Nan-Nan,&Huang, Xiao-Ying.(2015).From t2,2@bmmim to alkali@t2,2@bmmim ivory ball-like clusters: ionothermal syntheses, precise doping, and photocatalytic properties.Inorganic chemistry,54(12),5874-5878.
MLA Du, Cheng-Feng,et al."From t2,2@bmmim to alkali@t2,2@bmmim ivory ball-like clusters: ionothermal syntheses, precise doping, and photocatalytic properties".Inorganic chemistry 54.12(2015):5874-5878.
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