From t2,2@bmmim to alkali@t2,2@bmmim ivory ball-like clusters: ionothermal syntheses, precise doping, and photocatalytic properties | |
Du, Cheng-Feng1,2; Li, Jian-Rong1; Zhang, Bo1,2; Shen, Nan-Nan1,2; Huang, Xiao-Ying1 | |
刊名 | Inorganic chemistry |
2015-06-15 | |
卷号 | 54期号:12页码:5874-5878 |
ISSN号 | 0020-1669 |
DOI | 10.1021/acs.inorgchem.5b00652 |
通讯作者 | Li, jian-rong(jrli@fjirsm.ac.cn) |
英文摘要 | Presented here are the syntheses, structures, and properties of an in-sn-se compound based on a ternary super-supertetrahedral t2,2 cluster nested by bmrnirn cations and two of its alkali-doped quaternary analogues. by means of a one-pot ionothermal method, an alkali metal ion (cs+ or rb+) could be precisely doped into the central cavity of the cluster, forming an alkali@t2,2@bmmim quaternary cluster. remarkably, the undoped compound exhibited excellent stability and visible light photodegradation ability over a wide range of ph, especially in acidic conditions. |
WOS关键词 | VISIBLE-LIGHT ; IONIC LIQUIDS ; METHYL-ORANGE ; NANOCRYSTALS SYNTHESIS ; SHORT HISTORY ; DEGRADATION ; TIO2 ; NANOPARTICLES ; NANOMATERIALS ; NANOCLUSTER |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000356467100028 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2376394 |
专题 | 中国科学院大学 |
通讯作者 | Li, Jian-Rong |
作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Du, Cheng-Feng,Li, Jian-Rong,Zhang, Bo,et al. From t2,2@bmmim to alkali@t2,2@bmmim ivory ball-like clusters: ionothermal syntheses, precise doping, and photocatalytic properties[J]. Inorganic chemistry,2015,54(12):5874-5878. |
APA | Du, Cheng-Feng,Li, Jian-Rong,Zhang, Bo,Shen, Nan-Nan,&Huang, Xiao-Ying.(2015).From t2,2@bmmim to alkali@t2,2@bmmim ivory ball-like clusters: ionothermal syntheses, precise doping, and photocatalytic properties.Inorganic chemistry,54(12),5874-5878. |
MLA | Du, Cheng-Feng,et al."From t2,2@bmmim to alkali@t2,2@bmmim ivory ball-like clusters: ionothermal syntheses, precise doping, and photocatalytic properties".Inorganic chemistry 54.12(2015):5874-5878. |
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