Silver ion-mediated heterometallic three-fold interpenetrating uranyl organic framework | |
Mei, Lei1; Wu, Qun-yan1; An, Shu-wen1; Gao, Zeng-qiang2; Chai, Zhi-fang1,3,4; Shi, Wei-qun1 | |
刊名 | Inorganic chemistry |
2015-11-16 | |
卷号 | 54期号:22页码:10934-10945 |
ISSN号 | 0020-1669 |
DOI | 10.1021/acs.inorgchem.5b01988 |
通讯作者 | Shi, wei-qun(shiwq@ihep.ac.cn) |
英文摘要 | A unique case of a uranyl-silver heterometallic 3-fold interpenetrating network (u-ag-2,6-dcpca) from a multifunctionalized organic ligand, 2,6-dichloroisonicotinic acid, in the presence of uranyl and silver ions is reported. it is the first report of a heterometallic uranylorganic interpenetrating network or framework. notably, a (4,4)-connected uranyl building unit in u-ag-2,6-dcpca, which is available through combined influences of structural halogenation and silver ion additive on uranyl coordination, plays a vital role in the formation of a 3-fold interpenetrating network. halogen substitution effectively changes structural features and coordination behaviors of isonicotinate ligand and contributes to the control of uranyl coordination. meanwhile, it exerts influence on the stabilization of 3-fold interpenetrating networks by halogen-halogen interactions. theoretical calculation suggests that the silver ion should mainly serve as an inductive factor of uranyl species through strong ag-n binding affinity, directly leading to the formation of a (4,4)-connected uranyl building unit and finally a heterometallic 3-fold interpenetrating network. related experimental results, especially an interesting postsynthetic metalation, afford further evidence of this induction effect. |
WOS关键词 | PILLARED LAYER STRUCTURE ; COORDINATION POLYMERS ; ACTINIDE MATERIALS ; BASIS-SETS ; SUPRAMOLECULAR INCLUSION ; HALOGEN INTERACTIONS ; CRYSTAL-STRUCTURES ; HYBRID MATERIALS ; COMPLEXES ; URANIUM |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000364981300052 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2176444 |
专题 | 高能物理研究所 |
通讯作者 | Shi, Wei-qun |
作者单位 | 1.Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China 3.Soochow Univ, Sch Radiol & Interdisciplinary Sci, Suzhou 215123, Peoples R China 4.Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China |
推荐引用方式 GB/T 7714 | Mei, Lei,Wu, Qun-yan,An, Shu-wen,et al. Silver ion-mediated heterometallic three-fold interpenetrating uranyl organic framework[J]. Inorganic chemistry,2015,54(22):10934-10945. |
APA | Mei, Lei,Wu, Qun-yan,An, Shu-wen,Gao, Zeng-qiang,Chai, Zhi-fang,&Shi, Wei-qun.(2015).Silver ion-mediated heterometallic three-fold interpenetrating uranyl organic framework.Inorganic chemistry,54(22),10934-10945. |
MLA | Mei, Lei,et al."Silver ion-mediated heterometallic three-fold interpenetrating uranyl organic framework".Inorganic chemistry 54.22(2015):10934-10945. |
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