Interaction of poly(vinylpyrrolidone) with cationic and nonionic surfactants in aqueous solution studied by H-1 NMR

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	Interaction of poly(vinylpyrrolidone) with cationic and nonionic surfactants in aqueous solution studied by H-1 NMR
	Feng, Y ; Fang, XW ; Mao, SZ ; Zhao, S ; Yuan, HZ ; Yu, JY ; Du, YR
刊名	COLLOID AND POLYMER SCIENCE
	2003-09-01
卷号	281 期号:9 页码:902-906
关键词	poly(vinylpyrrolidone) cetyltrimethylammonium bromide Triton X-100 interaction relaxation time
英文摘要	Aqueous solutions of surfactant at various concentrations with 0.2% poly(vinylpyrrolidone) (PVP) were studied by H-1 NMR methods, including relaxation time and self-diffusion coefficient measurements and two-dimensional nuclear Overhauser enhancement spectroscopy. Two surfactants were concerned: cationic cetyltrimethylammonium bromide (CTAB) and nonionic Triton X-100 (TX-100). In the presence of 0.2% PVP, the variation of the T-2 values of CTAB protons is similar to that in the absence of PVP. Relaxation times of PVP protons are not significantly affected by the increasing concentration of CTAB. This indicates that no interaction between PVP and CTAB could be detected. However, in the presence of 0.2% PVP, TX-100 micelles are formed at a concentration lower than its normal critical micellization concentration. According to the results of relaxation time measurement of water protons, the presence of 0.2% PVP also induces the contraction of the hydrophilic layer of the TX-100 micelle. This indicates some interaction between PVP and TX-100, but the mechanism of this interaction needs further investigation.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical ; Polymer Science
研究领域[WOS]	Chemistry ; Polymer Science
关键词[WOS]	SODIUM DODECYL-SULFATE ; OVERHAUSER ENHANCEMENT SPECTROSCOPY ; NMR SELF-DIFFUSION ; TRITON X-100 ; CETYLTRIMETHYLAMMONIUM BROMIDE ; MIXED MICELLES ; WATER SOLUTION ; POLYMER ; MICELLIZATION ; AGGREGATION
收录类别	SCI
语种	英语
WOS记录号	WOS:000185116800015
公开日期	2015-12-08
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/8923]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
推荐引用方式 GB/T 7714	Feng, Y,Fang, XW,Mao, SZ,et al. Interaction of poly(vinylpyrrolidone) with cationic and nonionic surfactants in aqueous solution studied by H-1 NMR[J]. COLLOID AND POLYMER SCIENCE,2003,281(9):902-906.
APA	Feng, Y.,Fang, XW.,Mao, SZ.,Zhao, S.,Yuan, HZ.,...&Du, YR.(2003).Interaction of poly(vinylpyrrolidone) with cationic and nonionic surfactants in aqueous solution studied by H-1 NMR.COLLOID AND POLYMER SCIENCE,281(9),902-906.
MLA	Feng, Y,et al."Interaction of poly(vinylpyrrolidone) with cationic and nonionic surfactants in aqueous solution studied by H-1 NMR".COLLOID AND POLYMER SCIENCE 281.9(2003):902-906.