H-1 NMR studies of surfactants in aqueous solutions

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	H-1 NMR studies of surfactants in aqueous solutions
	Mao, SZ; Du, YR
刊名	ACTA PHYSICO-CHIMICA SINICA
	2003-07-01
卷号	19 期号:7 页码:675-680
关键词	NMR relaxation self-diffusion surfactant chemical shift
英文摘要	Surfactant is a substance that lowers the surface tension of the medium in which it is dissolved. They form oriented colloidal aggregates, micelles, when a specific concentration is exceeded and abrupt changes in physical properties of the solution will be observed. Surfactant systems have been proved to be very useful in many biological and industrial processes. Properties of these systems have been intensively investigated by many spectroscopy methods, especially proton nuclear magnetic resonance (H-1 NMR). It has played more and more important role in the continued development of NMR new techniques. Characterization of micellization processes, physical properties of micelles, e. g. structure, size and shape, hydration of micelles, solubilization by micelles, interaction between micelles of different kinds of surfactants, and that with biological compounds and with polymers were studied by the existing sophisticated NMR techniques. These investigations demonstrate that NMR spectroscopy is a versatile technique for the study of surfactants. It provides information at a molecular level that is not available by other spectroscopic methods. Chemical shift changes, relaxation experiments and NMR self-diffusion measurements are almost used routinely. The use of two-dimensional NMR spectroscopy, 2D NOESY and HOESY is a growing trend in studying the chain packing in micelles as well as interactions between micelles with other molecules, biological and polymeric. These methods provide a deeper insight into the relative arrangement of surfactant molecules in an associated assembly.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	NUCLEAR-MAGNETIC-RESONANCE ; OVERHAUSER EFFECT MEASUREMENTS ; SODIUM DODECYL-SULFATE ; PARAMAGNETIC RELAXATION METHOD ; NMR SELF-DIFFUSION ; MIXED MICELLES ; TRITON X-100 ; NONIONIC SURFACTANTS ; IONIC SURFACTANTS ; PROTON RELAXATION
收录类别	SCI
语种	英语
WOS记录号	WOS:000184412100023
公开日期	2015-12-08
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/8920]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
推荐引用方式 GB/T 7714	Mao, SZ,Du, YR. H-1 NMR studies of surfactants in aqueous solutions[J]. ACTA PHYSICO-CHIMICA SINICA,2003,19(7):675-680.
APA	Mao, SZ,&Du, YR.(2003).H-1 NMR studies of surfactants in aqueous solutions.ACTA PHYSICO-CHIMICA SINICA,19(7),675-680.
MLA	Mao, SZ,et al."H-1 NMR studies of surfactants in aqueous solutions".ACTA PHYSICO-CHIMICA SINICA 19.7(2003):675-680.