Self-aggregation of dendritic poly(benzyl ether)-poly(acrylic acid), an amphiphilic block copolymer, studied by H-1 NMR

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	Self-aggregation of dendritic poly(benzyl ether)-poly(acrylic acid), an amphiphilic block copolymer, studied by H-1 NMR
	Mao, SZ ; Zhu, LY ; Wang, TZ ; Li, MZ ; Wang, EJ ; Miao, XJ ; Fang, XW ; Yuan, HZ ; Du, YR
刊名	COLLOID AND POLYMER SCIENCE
	2002
卷号	280 期号:1 页码:90-94
关键词	self-diffusion coefficient NMR relaxation self-aggregate dendritic poly(benzyl ether)-poly(acrylic acid) amphiphilic block copolymer
英文摘要	The dynamic properties of the micelles of a novel synthesized amphiphilic block copolymer, dendritic poly(benzyl ether) -poly(acrylic acid) (Dendr.PBE-PAA), formed in aveous solutions were studied by the H-1 self-diffusion coefficient, relaxation measurements and 2D nuclear Overhauser enhancement spectroscopy. The experimental results show that Dendr.PBE-PAA molecules self-aggregate in aqueous solution. The dynamic properties of the Dendr.PBE-PAA micelles vary with their total concentration in the solution. The motion of the molecules in the micelles of a concentrated solution is more restricted than that in a less concentrated one. The main chains of PAA are densely packed in the surface layer of the hydrophobic core with the carboxyl side chain pointing to the aqueous medium and the hydrophobic phenoxy rings stay in the interior. The self-aggregate becomes larger as the degree of polymerization of PAA increases. However the phenoxy rings situated in the interior of the hydrophobic core become more loosely packed. n-Hexadecane is solubilized in the micelles. The optimal position of n-hexadecane is between the phenoxy rings next to the PAA chains.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical ; Polymer Science
研究领域[WOS]	Chemistry ; Polymer Science
关键词[WOS]	DIFFUSION ; MICELLES
收录类别	SCI
语种	英语
WOS记录号	WOS:000173550000014
公开日期	2015-12-08
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/8694]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	1.Chinese Acad Sci, State Key Lab, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
推荐引用方式 GB/T 7714	Mao, SZ,Zhu, LY,Wang, TZ,et al. Self-aggregation of dendritic poly(benzyl ether)-poly(acrylic acid), an amphiphilic block copolymer, studied by H-1 NMR[J]. COLLOID AND POLYMER SCIENCE,2002,280(1):90-94.
APA	Mao, SZ.,Zhu, LY.,Wang, TZ.,Li, MZ.,Wang, EJ.,...&Du, YR.(2002).Self-aggregation of dendritic poly(benzyl ether)-poly(acrylic acid), an amphiphilic block copolymer, studied by H-1 NMR.COLLOID AND POLYMER SCIENCE,280(1),90-94.
MLA	Mao, SZ,et al."Self-aggregation of dendritic poly(benzyl ether)-poly(acrylic acid), an amphiphilic block copolymer, studied by H-1 NMR".COLLOID AND POLYMER SCIENCE 280.1(2002):90-94.