Spectroscopic analysis of asymmetric top free radicals - Application to pure rotational spectra of NO2 in the ground vibronic state

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	Spectroscopic analysis of asymmetric top free radicals - Application to pure rotational spectra of NO2 in the ground vibronic state
	Liu, YY; Liu, XY; Liu, HP; Guo, YQ; Huang, GM; Lin, JL; Gao, H; Duan, CX
刊名	SCIENCE IN CHINA SERIES B-CHEMISTRY
	2001-02-01
卷号	44 期号:1 页码:7-16
关键词	asymmetric top free radical high-order centrifugal distortion spectroscopic analysis of NO2
英文摘要	Several key problems involved in the analyses of spectra of asymmetric top molecules, i.e., the effective Hamiltonian, the representation and basis vector, identification of energy levels, the selection rules, the relative intensity, and Zeeman tuning rate, were elucidated systematically. Introducing the high-order centrifugal distortion terms into the effective Hamiltonian, the precision for calculation has been improved substantially, which allows us to analyze the high-lying rotational transitions. A global analysis of all available spectra of (NO2)-N-14-O-16 in the ground vibronic state has been made to obtain a set of molecular constants of (NO2)-N-14-O-16 in the ground vibronic state which is the most precise and extensive so far. Using the improved parameters, some FIR LMR lines left unassigned hitherto have been identified successfully.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	SPIN-ROTATION ; RESONANCE ; (NO2)-N-14-O-16 ; MILLIMETER ; PARAMETERS
收录类别	SCI
语种	英语
WOS记录号	WOS:000167310000002
公开日期	2015-12-01
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/8584]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
推荐引用方式 GB/T 7714	Liu, YY,Liu, XY,Liu, HP,et al. Spectroscopic analysis of asymmetric top free radicals - Application to pure rotational spectra of NO2 in the ground vibronic state[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2001,44(1):7-16.
APA	Liu, YY.,Liu, XY.,Liu, HP.,Guo, YQ.,Huang, GM.,...&Duan, CX.(2001).Spectroscopic analysis of asymmetric top free radicals - Application to pure rotational spectra of NO2 in the ground vibronic state.SCIENCE IN CHINA SERIES B-CHEMISTRY,44(1),7-16.
MLA	Liu, YY,et al."Spectroscopic analysis of asymmetric top free radicals - Application to pure rotational spectra of NO2 in the ground vibronic state".SCIENCE IN CHINA SERIES B-CHEMISTRY 44.1(2001):7-16.