Compatibilization effect of graft copolymer on immiscible polymer blends: 1. LLDPE/SBS/LLDPE-g-PS systems
Feng, HQ; Ye, CH; Tian, J; Feng, ZL; Huang, BT
刊名POLYMER
1998-05-01
卷号39期号:10页码:1787-1792
关键词C-13 CPMAS nmr dsc graft copolymer
英文摘要compatibilizing effect of graft copolymer, linear low density polyethylene-g-polystyrene (LLDPE-g-PS), on immiscible blends of LLDPE with styrene-butadiene-styrene triblock copolymer (SBS) has been investigated by means of C-13 CPMAS n.m.r. and d.s.c. techniques. The results indicate that LLDPE-g-PS is an effective compatibilizer for LLDPE/SBS blends. It was found that LLDPE-g-PS chains connect two immiscible components, LLDPE and SBS, through solubilization of chemically identical segments of LLDPE-g-PS into the amorphous region of LLDPE acid PS block domain of SBS, respectively. It was also found that LLDPE-g-PS chains connect the crystalline region of LLDPE by isomorphism, with serious effects on the supermolecular structure of LLDPE. The effect of LLDPE-g-PS on the supermolecular structure of LLDPE in the LLDPE/SBS blends obviously depends on the composition of the blends, but has little dependence on the PS grafting yields of LLDPE-g-PS. (C) 1998 Elsevier Science Ltd. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Polymer Science
研究领域[WOS]Polymer Science
关键词[WOS]NUCLEAR MAGNETIC-RESONANCE ; BLOCK COPOLYMERS ; C-13 NMR ; MOLECULAR DESIGN ; SPIN DIFFUSION ; POLYPROPYLENE ; POLYETHYLENE ; INTERFACE ; PHASE
收录类别SCI
语种英语
WOS记录号WOS:000072456500004
公开日期2015-12-01
内容类型期刊论文
源URL[http://ir.wipm.ac.cn/handle/112942/8350]  
专题武汉物理与数学研究所_2011年以前论文发表(包括2011年)
作者单位1.Chinese Acad Sci, Wuhan Inst Phys, Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Phys Lab, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Feng, HQ,Ye, CH,Tian, J,et al. Compatibilization effect of graft copolymer on immiscible polymer blends: 1. LLDPE/SBS/LLDPE-g-PS systems[J]. POLYMER,1998,39(10):1787-1792.
APA Feng, HQ,Ye, CH,Tian, J,Feng, ZL,&Huang, BT.(1998).Compatibilization effect of graft copolymer on immiscible polymer blends: 1. LLDPE/SBS/LLDPE-g-PS systems.POLYMER,39(10),1787-1792.
MLA Feng, HQ,et al."Compatibilization effect of graft copolymer on immiscible polymer blends: 1. LLDPE/SBS/LLDPE-g-PS systems".POLYMER 39.10(1998):1787-1792.
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