Compatibilization effect of graft copolymer on immiscible polymer blends: 1. LLDPE/SBS/LLDPE-g-PS systems | |
Feng, HQ; Ye, CH; Tian, J; Feng, ZL; Huang, BT | |
刊名 | POLYMER
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1998-05-01 | |
卷号 | 39期号:10页码:1787-1792 |
关键词 | C-13 CPMAS nmr dsc graft copolymer |
英文摘要 | compatibilizing effect of graft copolymer, linear low density polyethylene-g-polystyrene (LLDPE-g-PS), on immiscible blends of LLDPE with styrene-butadiene-styrene triblock copolymer (SBS) has been investigated by means of C-13 CPMAS n.m.r. and d.s.c. techniques. The results indicate that LLDPE-g-PS is an effective compatibilizer for LLDPE/SBS blends. It was found that LLDPE-g-PS chains connect two immiscible components, LLDPE and SBS, through solubilization of chemically identical segments of LLDPE-g-PS into the amorphous region of LLDPE acid PS block domain of SBS, respectively. It was also found that LLDPE-g-PS chains connect the crystalline region of LLDPE by isomorphism, with serious effects on the supermolecular structure of LLDPE. The effect of LLDPE-g-PS on the supermolecular structure of LLDPE in the LLDPE/SBS blends obviously depends on the composition of the blends, but has little dependence on the PS grafting yields of LLDPE-g-PS. (C) 1998 Elsevier Science Ltd. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Polymer Science |
研究领域[WOS] | Polymer Science |
关键词[WOS] | NUCLEAR MAGNETIC-RESONANCE ; BLOCK COPOLYMERS ; C-13 NMR ; MOLECULAR DESIGN ; SPIN DIFFUSION ; POLYPROPYLENE ; POLYETHYLENE ; INTERFACE ; PHASE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000072456500004 |
公开日期 | 2015-12-01 |
内容类型 | 期刊论文 |
源URL | [http://ir.wipm.ac.cn/handle/112942/8350] ![]() |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys, Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Phys Lab, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Feng, HQ,Ye, CH,Tian, J,et al. Compatibilization effect of graft copolymer on immiscible polymer blends: 1. LLDPE/SBS/LLDPE-g-PS systems[J]. POLYMER,1998,39(10):1787-1792. |
APA | Feng, HQ,Ye, CH,Tian, J,Feng, ZL,&Huang, BT.(1998).Compatibilization effect of graft copolymer on immiscible polymer blends: 1. LLDPE/SBS/LLDPE-g-PS systems.POLYMER,39(10),1787-1792. |
MLA | Feng, HQ,et al."Compatibilization effect of graft copolymer on immiscible polymer blends: 1. LLDPE/SBS/LLDPE-g-PS systems".POLYMER 39.10(1998):1787-1792. |
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