Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen | |
Wang, Lianyue1,2,3; Li, Jun1,3; Lv, Ying1,3; Zhao, Gongda1,3; Gao, Shuang1,3 | |
刊名 | synlett
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2012-04-01 | |
期号 | 7页码:1074-1078 |
关键词 | palladium oxidation furans alkynes molecular oxygen |
英文摘要 | a new approach to the synthesis of tetrasubstituted furans using aromatic alkynes catalyzed by pdcl2 in dma (n,n-dimethylacetamide)-h2o with dioxygen as the sole oxidant is described, in which the oxygen atom of the furan was from water. the preliminary mechanistic understanding of this transformation was investigated. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, organic |
研究领域[WOS] | chemistry |
关键词[WOS] | efficient synthesis ; polysubstituted furans ; substituted furans ; mild conditions ; cycloisomerization ; transformation ; heterocycles ; ketones ; alkynes ; (z)-2-en-4-yn-1-ols |
收录类别 | SCI ; CCR |
语种 | 英语 |
WOS记录号 | WOS:000302858500018 |
公开日期 | 2015-11-17 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/143141] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.DNL, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Lianyue,Li, Jun,Lv, Ying,et al. Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen[J]. synlett,2012(7):1074-1078. |
APA | Wang, Lianyue,Li, Jun,Lv, Ying,Zhao, Gongda,&Gao, Shuang.(2012).Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen.synlett(7),1074-1078. |
MLA | Wang, Lianyue,et al."Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen".synlett .7(2012):1074-1078. |
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