Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen

	Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen
	Wang, Lianyue 1,2,3; Li, Jun 1,3; Lv, Ying 1,3; Zhao, Gongda 1,3; Gao, Shuang 1,3
刊名	synlett
	2012-04-01
期号	7 页码:1074-1078
关键词	palladium oxidation furans alkynes molecular oxygen
英文摘要	a new approach to the synthesis of tetrasubstituted furans using aromatic alkynes catalyzed by pdcl2 in dma (n,n-dimethylacetamide)-h2o with dioxygen as the sole oxidant is described, in which the oxygen atom of the furan was from water. the preliminary mechanistic understanding of this transformation was investigated.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	efficient synthesis ; polysubstituted furans ; substituted furans ; mild conditions ; cycloisomerization ; transformation ; heterocycles ; ketones ; alkynes ; (z)-2-en-4-yn-1-ols
收录类别	SCI ; CCR
语种	英语
WOS记录号	WOS:000302858500018
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/143141]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.DNL, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Wang, Lianyue,Li, Jun,Lv, Ying,et al. Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen[J]. synlett,2012(7):1074-1078.
APA	Wang, Lianyue,Li, Jun,Lv, Ying,Zhao, Gongda,&Gao, Shuang.(2012).Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen.synlett(7),1074-1078.
MLA	Wang, Lianyue,et al."Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen".synlett .7(2012):1074-1078.