The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2

	The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2
	Shen Liusi 1; Qi Fei 1; Zhang Yunwu 1; Chen Wenwu 2; Wang Zhaohui 2; Ding Chuanfan 2; Kong Fanao 2
刊名	acta physico-chimica sinica
	1995
卷号	11 期号:10 页码:870-872
关键词	Si(CH3)(2)Cl-2 Syrchrotron radiation Photoionization Ionization potential Chemical bond energy
英文摘要	the vacuum ultraviolet photoionization spectrum of si(ch3)(2)cl-2 has been obtained with synchrotron radiation source. the adiabatic ionization potential of si(ch3)(2)cl-2 is 10.62 +/- 0.03ev (0.37ev lower than reported by pes), and the appearance potentials for si(ch3)cl-2(+), si(ch3)(2)cl+, sich3+ and sicl+ are 11.25 +/- 0.03ev, 12.69 +/- 0.04ev, 15.1 +/- 0.1ev and 21.16ev +/- 0.1ev respectively. from these results, we estimate d(si(ch3)cl-2(+)-ch3)=0.63 +/- 0.03ev and d(si(ch3)(2)cl+-cl))=2.07 +/- 0.04ev.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
收录类别	SCI
语种	英语
WOS记录号	WOS:000207590900002
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/142766]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Univ Sci & Technol China, Natl Lab Synchrotron Radiat, Hefei 230027, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Shen Liusi,Qi Fei,Zhang Yunwu,et al. The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2[J]. acta physico-chimica sinica,1995,11(10):870-872.
APA	Shen Liusi.,Qi Fei.,Zhang Yunwu.,Chen Wenwu.,Wang Zhaohui.,...&Kong Fanao.(1995).The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2.acta physico-chimica sinica,11(10),870-872.
MLA	Shen Liusi,et al."The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2".acta physico-chimica sinica 11.10(1995):870-872.