DYNAMICS OF THE CHEMILUMINESCENT REACTIONS OF Ba+CL2, Br-2-FORMATION MECHANISM OF THE ELECTRONICALLY EXCITED BaCl2*
Lu Richang; Li Fue; Li Jian; Peng Lianshun; Liu Haisheng; He Guozhong; Lou Nanquan
刊名acta physico-chimica sinica
1988
卷号4期号:4页码:387-392
英文摘要the chemilumtnescent reactions of ba + cl-2, were carried out in a beamgas apparatus and the cl spectra have been observed. the continuum in the visible region of the cl spectrum has been asigned as the emission of bacl2*, but there is a discrepancy about the mechanism of formation of bacl2*. the observed quadratic dependences of the bacl2* intensity on cl-2 pressure (fig.1), the ba intensity upon the ba atom number density (fig.3) and the independence of the bacl2* emission upon thp ba atom number density in the high density region (fig.2) imply that the two body recombination radiation or the dimmer ba-2 exchange rdectitn ba-2 + cl-2 should be neglected. no enhancement but a slight drop of the bacl2* intenaity with increasing n-2 mixed with cl-2 indicates that the three body stabilization route can be excluded as well.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
收录类别SCI
语种英语
WOS记录号WOS:000207571500012
公开日期2015-11-17
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/142755]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Beijing 100864, Peoples R China
推荐引用方式
GB/T 7714
Lu Richang,Li Fue,Li Jian,et al. DYNAMICS OF THE CHEMILUMINESCENT REACTIONS OF Ba+CL2, Br-2-FORMATION MECHANISM OF THE ELECTRONICALLY EXCITED BaCl2*[J]. acta physico-chimica sinica,1988,4(4):387-392.
APA Lu Richang.,Li Fue.,Li Jian.,Peng Lianshun.,Liu Haisheng.,...&Lou Nanquan.(1988).DYNAMICS OF THE CHEMILUMINESCENT REACTIONS OF Ba+CL2, Br-2-FORMATION MECHANISM OF THE ELECTRONICALLY EXCITED BaCl2*.acta physico-chimica sinica,4(4),387-392.
MLA Lu Richang,et al."DYNAMICS OF THE CHEMILUMINESCENT REACTIONS OF Ba+CL2, Br-2-FORMATION MECHANISM OF THE ELECTRONICALLY EXCITED BaCl2*".acta physico-chimica sinica 4.4(1988):387-392.
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