Chiral ferrocenyl phosphine-phosphoramidite ligands for Cu-catalyzed asymmetric conjugate reduction of alpha,beta-unsaturated esters

	Chiral ferrocenyl phosphine-phosphoramidite ligands for Cu-catalyzed asymmetric conjugate reduction of alpha,beta-unsaturated esters
	Hou, Chuan-Jin 1,2; Guo, Wei-Lei 1,2; Hu, Xiang-Ping 1; Deng, Jun 1; Zheng, Zhuo 1
刊名	tetrahedron-asymmetry
	2011-01-31
卷号	22 期号:2 页码:195-199
英文摘要	unsymmetrical hybrid chiral ferrocenyl phosphine-phosphoramidite ligands have been applied for the first time in the cu-catalyzed asymmetric 1,4-reduction of beta-aryl substituted alpha,beta-unsaturated esters. the results show that the ligand bearing (s(c))-central, (r(p))-planar, and (r(a))-axial chiralities gave the best performance. the present catalytic system proved to be highly substrate-dependent, catalyzing the conjugate reduction of alpha,beta-unsaturated esters in moderate to excellent enantioselectivities. (c) 2011 elsevier ltd. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, inorganic & nuclear ; chemistry, organic ; chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	highly enantioselective hydrogenation ; dynamic kinetic-resolution ; acid-derivatives ; roche ester ; hydroformylation ; indolphos ; efficient ; 1,4-reductions ; quinaphos ; ketones
收录类别	SCI ; CCR
语种	英语
WOS记录号	WOS:000288890800012
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/142526]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Polytech Univ, Sch Chem & Mat, Dalian 116034, Peoples R China
推荐引用方式 GB/T 7714	Hou, Chuan-Jin,Guo, Wei-Lei,Hu, Xiang-Ping,et al. Chiral ferrocenyl phosphine-phosphoramidite ligands for Cu-catalyzed asymmetric conjugate reduction of alpha,beta-unsaturated esters[J]. tetrahedron-asymmetry,2011,22(2):195-199.
APA	Hou, Chuan-Jin,Guo, Wei-Lei,Hu, Xiang-Ping,Deng, Jun,&Zheng, Zhuo.(2011).Chiral ferrocenyl phosphine-phosphoramidite ligands for Cu-catalyzed asymmetric conjugate reduction of alpha,beta-unsaturated esters.tetrahedron-asymmetry,22(2),195-199.
MLA	Hou, Chuan-Jin,et al."Chiral ferrocenyl phosphine-phosphoramidite ligands for Cu-catalyzed asymmetric conjugate reduction of alpha,beta-unsaturated esters".tetrahedron-asymmetry 22.2(2011):195-199.