Crossed Beams Study on the Dynamics of F Atom Reaction with 1,2-Butadiene

	Crossed Beams Study on the Dynamics of F Atom Reaction with 1,2-Butadiene
	Xiao, Chong-fa; Shen, Guan-lin; Wang, Xiu-yan; Yang, Xue-ming
刊名	chinese journal of chemical physics
	2010-12-01
卷号	23 期号:6 页码:621-625
关键词	Fluorine atom 1 S(N)2 mechanism Universal crossed molecular beam 2-Butadiene
英文摘要	we have investigated the dynamics of the f+c4h6 reaction using the universal crossed molecular beam method. the c4h5f+h reaction channel was observed in this experiment. angular resolved time-of-flight spectra have been measured for the c4h5f product. product angular distributions as well as kinetic energy distributions were determined for this product channel. experimental results show that the c4h5f product is largely backward scattered with considerable forward scattering signal, relative to the f atom beam direction. this suggests that the reaction channel mainly proceeds via a long-lived complex formation mechanism, with possible contribution from a direct s(n)2 type mechanism.
WOS标题词	science & technology ; physical sciences
类目[WOS]	physics, atomic, molecular & chemical
研究领域[WOS]	physics
关键词[WOS]	molecular-beam ; scattering dynamics ; f+cd4 reaction ; shock-tube ; ab-initio ; 193 nm ; decomposition ; photochemistry ; isomers ; photodissociation
收录类别	SCI
语种	英语
WOS记录号	WOS:000286298900001
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/142269]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Xiao, Chong-fa,Shen, Guan-lin,Wang, Xiu-yan,et al. Crossed Beams Study on the Dynamics of F Atom Reaction with 1,2-Butadiene[J]. chinese journal of chemical physics,2010,23(6):621-625.
APA	Xiao, Chong-fa,Shen, Guan-lin,Wang, Xiu-yan,&Yang, Xue-ming.(2010).Crossed Beams Study on the Dynamics of F Atom Reaction with 1,2-Butadiene.chinese journal of chemical physics,23(6),621-625.
MLA	Xiao, Chong-fa,et al."Crossed Beams Study on the Dynamics of F Atom Reaction with 1,2-Butadiene".chinese journal of chemical physics 23.6(2010):621-625.