Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24]

	Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24]
	Lue, Hongying 1; Zhang, Yongna 2; Jiang, Zongxuan 2; Li, Can 2
刊名	green chemistry
	2010
卷号	12 期号:11 页码:1954-1958
英文摘要	benzothiophene (bt), dibenzothiophene (dbt) and 4,6-dimethyldibenzothiophene (4,6-dmdbt) are oxidized to their corresponding sulfones by an anderson-type catalyst [(c18h37)(2)n(ch3)(2)](5)imo6o24 using molecular oxygen as the oxidant under mild reaction conditions. these refractory sulfur-containing compounds can be oxidized completely in the absence of any sacrificial agent. solvents such as acetonitrile and water play a negative effect on the oxidative desulfurization system. the catalytic activities of the amphiphilic anderson catalysts depend on the quaternary ammonium cations. the reactivity of the sulfur-containing compounds follows the order 4,6-dmdbt > dbt > bt.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	ultra-deep desulfurization ; selective oxidation ; molecular-oxygen ; chemical oxidation ; emulsion droplets ; hydrogen-peroxide ; diesel fuel ; acid ; hexamolybdochromate(iii) ; extraction
收录类别	SCI ; CCR
语种	英语
WOS记录号	WOS:000283936800012
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/142195]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Yantai Univ, Sci & Engn Coll Chem & Biol, Yantai 264005, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Lue, Hongying,Zhang, Yongna,Jiang, Zongxuan,et al. Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24][J]. green chemistry,2010,12(11):1954-1958.
APA	Lue, Hongying,Zhang, Yongna,Jiang, Zongxuan,&Li, Can.(2010).Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24].green chemistry,12(11),1954-1958.
MLA	Lue, Hongying,et al."Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24]".green chemistry 12.11(2010):1954-1958.