Aqueous hydrogenolysis of glycerol over Ni-Ce/AC catalyst: Promoting effect of Ce on catalytic performance | |
Yu, Weiqiang1,2; Zhao, Jing1,2; Ma, Hong1; Miao, Hong1; Song, Qi1,2; Xu, Jie1 | |
刊名 | applied catalysis a-general
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2010-07-31 | |
卷号 | 383期号:1-2页码:73-78 |
关键词 | Aqueous hydrogenolysis Cerium Glycerol Nickel |
英文摘要 | the aqueous hydrogenolysis of glycerol was performed over ni-ce/ac catalyst. the addition of cerium showed a remarkable promoting effect on the catalytic performance compared with other metals including copper, tin, zinc, aluminum, iron and cobalt. for example, 90.4% of glycerol conversion could be achieved at 473 k under 5 mpa of h(2) with 6 h. the ni-ce/ac catalysts were characterized by n(2) physisorption, xrd, tem, nh(3)-tpd and h(2)-tpr. the results showed that the addition of cerium to the ni/ac catalyst greatly changed the reductive behavior. (c) 2010 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
类目[WOS] | chemistry, physical ; environmental sciences |
研究领域[WOS] | chemistry ; environmental sciences & ecology |
关键词[WOS] | vapor-phase hydrogenation ; amorphous alloy catalyst ; propylene-glycol ; selective hydrogenolysis ; nickel ; crotonaldehyde ; conversion ; phenol ; acid |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000280624900009 |
公开日期 | 2015-11-17 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/141688] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Yu, Weiqiang,Zhao, Jing,Ma, Hong,et al. Aqueous hydrogenolysis of glycerol over Ni-Ce/AC catalyst: Promoting effect of Ce on catalytic performance[J]. applied catalysis a-general,2010,383(1-2):73-78. |
APA | Yu, Weiqiang,Zhao, Jing,Ma, Hong,Miao, Hong,Song, Qi,&Xu, Jie.(2010).Aqueous hydrogenolysis of glycerol over Ni-Ce/AC catalyst: Promoting effect of Ce on catalytic performance.applied catalysis a-general,383(1-2),73-78. |
MLA | Yu, Weiqiang,et al."Aqueous hydrogenolysis of glycerol over Ni-Ce/AC catalyst: Promoting effect of Ce on catalytic performance".applied catalysis a-general 383.1-2(2010):73-78. |
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