Aqueous hydrogenolysis of glycerol over Ni-Ce/AC catalyst: Promoting effect of Ce on catalytic performance

	Aqueous hydrogenolysis of glycerol over Ni-Ce/AC catalyst: Promoting effect of Ce on catalytic performance
	Yu, Weiqiang 1,2; Zhao, Jing 1,2; Ma, Hong 1; Miao, Hong 1; Song, Qi 1,2; Xu, Jie 1
刊名	applied catalysis a-general
	2010-07-31
卷号	383 期号:1-2 页码:73-78
关键词	Aqueous hydrogenolysis Cerium Glycerol Nickel
英文摘要	the aqueous hydrogenolysis of glycerol was performed over ni-ce/ac catalyst. the addition of cerium showed a remarkable promoting effect on the catalytic performance compared with other metals including copper, tin, zinc, aluminum, iron and cobalt. for example, 90.4% of glycerol conversion could be achieved at 473 k under 5 mpa of h(2) with 6 h. the ni-ce/ac catalysts were characterized by n(2) physisorption, xrd, tem, nh(3)-tpd and h(2)-tpr. the results showed that the addition of cerium to the ni/ac catalyst greatly changed the reductive behavior. (c) 2010 elsevier b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences ; life sciences & biomedicine
类目[WOS]	chemistry, physical ; environmental sciences
研究领域[WOS]	chemistry ; environmental sciences & ecology
关键词[WOS]	vapor-phase hydrogenation ; amorphous alloy catalyst ; propylene-glycol ; selective hydrogenolysis ; nickel ; crotonaldehyde ; conversion ; phenol ; acid
收录类别	SCI
语种	英语
WOS记录号	WOS:000280624900009
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/141688]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yu, Weiqiang,Zhao, Jing,Ma, Hong,et al. Aqueous hydrogenolysis of glycerol over Ni-Ce/AC catalyst: Promoting effect of Ce on catalytic performance[J]. applied catalysis a-general,2010,383(1-2):73-78.
APA	Yu, Weiqiang,Zhao, Jing,Ma, Hong,Miao, Hong,Song, Qi,&Xu, Jie.(2010).Aqueous hydrogenolysis of glycerol over Ni-Ce/AC catalyst: Promoting effect of Ce on catalytic performance.applied catalysis a-general,383(1-2),73-78.
MLA	Yu, Weiqiang,et al."Aqueous hydrogenolysis of glycerol over Ni-Ce/AC catalyst: Promoting effect of Ce on catalytic performance".applied catalysis a-general 383.1-2(2010):73-78.