Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms | |
Zhang, Zeng-Guang; Xu, Hong-Guang; Feng, Yuan; Zheng, Weijun | |
刊名 | journal of chemical physics
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2010-04-28 | |
卷号 | 132期号:16 |
英文摘要 | we investigated alns- (n=3-15) and alns2- (n=7-15) clusters with mass spectrometry and photoelectron spectroscopy. we found that al-13 is relatively robust when it reacts with sulfur atoms, indicating that it has some superatomic character. however, al-13 cannot be simply considered as a superatom when it interacts with sulfur due to the following reasons: al-13's icosahedral structure has been distorted slightly by sulfur atoms; the vertical detachment energies and adiabatic detachment energies of al13s- and al13s2- clusters are not significantly different from those of their neighboring clusters; and the charge distributions in al13s- and al13s2- do not necessarily associate with superatomic behavior of al-13. (c) 2010 american institute of physics. [doi: 10.1063/1.3374431] |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | physics, atomic, molecular & chemical |
研究领域[WOS] | physics |
关键词[WOS] | charged aluminum clusters ; photoelectron-spectroscopy ; anions ; search ; metal |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000277241500003 |
公开日期 | 2015-11-17 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/141679] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Zeng-Guang,Xu, Hong-Guang,Feng, Yuan,et al. Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms[J]. journal of chemical physics,2010,132(16). |
APA | Zhang, Zeng-Guang,Xu, Hong-Guang,Feng, Yuan,&Zheng, Weijun.(2010).Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms.journal of chemical physics,132(16). |
MLA | Zhang, Zeng-Guang,et al."Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms".journal of chemical physics 132.16(2010). |
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