Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms

	Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms
	Zhang, Zeng-Guang; Xu, Hong-Guang; Feng, Yuan; Zheng, Weijun
刊名	journal of chemical physics
	2010-04-28
卷号	132 期号:16
英文摘要	we investigated alns- (n=3-15) and alns2- (n=7-15) clusters with mass spectrometry and photoelectron spectroscopy. we found that al-13 is relatively robust when it reacts with sulfur atoms, indicating that it has some superatomic character. however, al-13 cannot be simply considered as a superatom when it interacts with sulfur due to the following reasons: al-13's icosahedral structure has been distorted slightly by sulfur atoms; the vertical detachment energies and adiabatic detachment energies of al13s- and al13s2- clusters are not significantly different from those of their neighboring clusters; and the charge distributions in al13s- and al13s2- do not necessarily associate with superatomic behavior of al-13. (c) 2010 american institute of physics. [doi: 10.1063/1.3374431]
WOS标题词	science & technology ; physical sciences
类目[WOS]	physics, atomic, molecular & chemical
研究领域[WOS]	physics
关键词[WOS]	charged aluminum clusters ; photoelectron-spectroscopy ; anions ; search ; metal
收录类别	SCI
语种	英语
WOS记录号	WOS:000277241500003
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/141679]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Zeng-Guang,Xu, Hong-Guang,Feng, Yuan,et al. Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms[J]. journal of chemical physics,2010,132(16).
APA	Zhang, Zeng-Guang,Xu, Hong-Guang,Feng, Yuan,&Zheng, Weijun.(2010).Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms.journal of chemical physics,132(16).
MLA	Zhang, Zeng-Guang,et al."Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms".journal of chemical physics 132.16(2010).