Morphology-dependent redox and catalytic properties of CeO2 nanostructures: Nanowires, nanorods and nanoparticles
Tana1,2; Zhang, Milin2; Li, Juan1; Li, Huaju1; Li, Yong1; Shen, Wenjie1
刊名catalysis today
2009-10-30
卷号148期号:1-2页码:179-183
关键词Nanomaterials CeO2 Catalysts Redox Morphology-dependence
英文摘要the redox features and the catalytic activities of ceria nanowires, nanorods and nanoparticles were comparatively studied. the morphol ogy-depen dent phenomenon is closely related to the nature of the exposed crystal planes. the ceo2 nanoparticles mainly expose the stable {1 1 1} plane on the surface, whereas the rod-shaped nanostructures preferentially expose the reactive {1 1 0} and {1 0 0} planes, giving higher oxygen storage capacity and catalytic activity for co oxidation, although both the ceo2 nanorods and the ceo2 nanowires predominantly expose the reactive {1 1 0} and {1 0 0} planes, the ceo2 nanowires favor to expose a large proportion of active planes on the surface, resulting in a much higher activity for co oxidation than the nanorods. (c) 2009 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; engineering, chemical
研究领域[WOS]chemistry ; engineering
关键词[WOS]co oxidation ; ceria ; oxygen ; nanotubes ; surfaces ; adsorption ; films
收录类别SCI
语种英语
WOS记录号WOS:000271830100030
公开日期2015-11-17
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/141498]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China
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Tana,Zhang, Milin,Li, Juan,et al. Morphology-dependent redox and catalytic properties of CeO2 nanostructures: Nanowires, nanorods and nanoparticles[J]. catalysis today,2009,148(1-2):179-183.
APA Tana,Zhang, Milin,Li, Juan,Li, Huaju,Li, Yong,&Shen, Wenjie.(2009).Morphology-dependent redox and catalytic properties of CeO2 nanostructures: Nanowires, nanorods and nanoparticles.catalysis today,148(1-2),179-183.
MLA Tana,et al."Morphology-dependent redox and catalytic properties of CeO2 nanostructures: Nanowires, nanorods and nanoparticles".catalysis today 148.1-2(2009):179-183.
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