1-Lithio-1,3-dienes as useful building blocks in organic synthesis

	1-Lithio-1,3-dienes as useful building blocks in organic synthesis
	Zhang, Wen-Xiong; Xi, Zhenfeng
刊名	pure and applied chemistry
	2009-02-01
卷号	81 期号:2 页码:235-246
关键词	organolithium reagents lithio-1 carbonyllithium carbolithiation lithioketimines 3-butadienes
英文摘要	both intermolecular reactivities toward c-o and c-n unsaturated substrates and intramolecular reactions of various 1-lithio-1,3-dienes are briefly summarized. results reveal that intramolecular synergy between the alkenyllithium moiety and the butadienyl skeleton make 1-lithio-1,3-diene derivatives useful and unique as building blocks in organic synthesis. it is demonstrated that substitution patterns and the nature of the substituents on the butadienyl skeleton have remarkable effects on reaction pathways.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	fischer carbene complexes ; dearomatizing anionic cyclization ; transition-metal-complexes ; efficient synthesis ; carbon-monoxide ; cyclopentadiene derivatives ; electrophilic cyclization ; stereoselective-synthesis ; skeletal rearrangement ; benzopyranylidenetungsten(0) complexes
收录类别	SCI ; ISTP
语种	英语
WOS记录号	WOS:000263531100007
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/141465]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Wen-Xiong,Xi, Zhenfeng. 1-Lithio-1,3-dienes as useful building blocks in organic synthesis[J]. pure and applied chemistry,2009,81(2):235-246.
APA	Zhang, Wen-Xiong,&Xi, Zhenfeng.(2009).1-Lithio-1,3-dienes as useful building blocks in organic synthesis.pure and applied chemistry,81(2),235-246.
MLA	Zhang, Wen-Xiong,et al."1-Lithio-1,3-dienes as useful building blocks in organic synthesis".pure and applied chemistry 81.2(2009):235-246.