VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl

	VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl
	Li Hongzhi; Wang Xuebin; Kong Fanao; Zhu Qihe
刊名	acta physico-chimica sinica
	1993
卷号	9 期号:4 页码:447-449
关键词	Intramolecular energy transfer IR emission spectroscopy Heavy atom effect Chlorotrimethylsilane
英文摘要	the vibrationally excited oh(v) from the reaction of o(d-1)+si(ch3)(3)cl was observed by uv lasre photolysis/ftir emission spectroscopy. the vibrational number was only up to 3 with a ratio of 1:0.3:0 1 for v=1:2:3. comparing this result with the similar reaction of o(d-1) + si(ch3)(4) which oh(v) vibrational number was high up to 4 with a ration of 1:1:1:0:3 for v=1:2:3:4 under the same experimental conditions, it was found that the substitution of cl for ch3 affected the extent of heavy si atom blooking the energy migratio in a molecule. this results identifies the prediction that the characteristic of electrons in central atom plays an important role in intramolecular energy transfer.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
收录类别	SCI
语种	英语
WOS记录号	WOS:000207577600004
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/141380]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Li Hongzhi,Wang Xuebin,Kong Fanao,et al. VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl[J]. acta physico-chimica sinica,1993,9(4):447-449.
APA	Li Hongzhi,Wang Xuebin,Kong Fanao,&Zhu Qihe.(1993).VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl.acta physico-chimica sinica,9(4),447-449.
MLA	Li Hongzhi,et al."VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl".acta physico-chimica sinica 9.4(1993):447-449.