Synthesis and applications of mesoporous Cu-Zn-Al2O3 catalyst for dehydrogenation of 2-butanol

	Synthesis and applications of mesoporous Cu-Zn-Al2O3 catalyst for dehydrogenation of 2-butanol
	Fang, Deren 1,2; Ren, Wanzhong 2; Liu, Zhongmin 1; Xu, Xiufeng 2; Xu, Lei 1; Lue, Hongying 2; Liao, Weiping 2; Zhang, Huimin 2
刊名	journal of natural gas chemistry
	2009-06-01
卷号	18 期号:2 页码:179-182
关键词	Cu-Zn-Al2O3 mesoporous materials dehydrogenation of 2-butanol catalyst
英文摘要	a series of mesoporous cu-zn-al2o3 materials have been synthesized at ambient temperature and their structure was characterized by xrd, n-2 physical adsorption and tpr techniques. their catalytic applications for the dehydrogenation of 2-butanol to methyl ethyl ketone (mek) were evaluated in a fixed-bed flow reactor at atmospheric pressure. it is demonstrated from the xrd patterns that both the as-synthesized samples and calcined samples have the typical xrd patterns of meso-structured materials and the results of n2o chemical adsorption showed that cu was embedded in the framework of the mesoporous materials and homogeneously dispersed in the mesoporous cu-zn-al2o3 materials. the catalytic activity of 2-butanol dehydrogenation was varied in the order of cza(10)< cza(cp)< cza(20)< cza(30) while the selectivity of mek was increased in the order of cza(cp)cza(10)< cza(20)< cza(30).
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, applied ; chemistry, physical ; energy & fuels ; engineering, chemical
研究领域[WOS]	chemistry ; energy & fuels ; engineering
关键词[WOS]	copper-containing catalysts ; co-mo catalyst ; oxidation-state ; mcm-41 ; hydrodesulfurization ; cyclohexanol ; isopropanol ; sites
收录类别	SCI
语种	英语
WOS记录号	WOS:000267854100010
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/141326]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Yantai Univ, Inst Appl Catalysis, Yantai 264005, Shandong, Peoples R China
推荐引用方式 GB/T 7714	Fang, Deren,Ren, Wanzhong,Liu, Zhongmin,et al. Synthesis and applications of mesoporous Cu-Zn-Al2O3 catalyst for dehydrogenation of 2-butanol[J]. journal of natural gas chemistry,2009,18(2):179-182.
APA	Fang, Deren.,Ren, Wanzhong.,Liu, Zhongmin.,Xu, Xiufeng.,Xu, Lei.,...&Zhang, Huimin.(2009).Synthesis and applications of mesoporous Cu-Zn-Al2O3 catalyst for dehydrogenation of 2-butanol.journal of natural gas chemistry,18(2),179-182.
MLA	Fang, Deren,et al."Synthesis and applications of mesoporous Cu-Zn-Al2O3 catalyst for dehydrogenation of 2-butanol".journal of natural gas chemistry 18.2(2009):179-182.