Fe2O3/SBA-15 catalyst synthesized by chemical vapor infiltration for Friedel-Crafts alkylation reaction | |
Lei, Zhibin1; Bai, Shiying1; Dang, Liqin1; Xia, Haian2; Xu, Qian2; Cao, Yindi1; An, Lizhen1; Zhao, Mingyi1; Lo, An-Ya3; Liu, Shang-Bin3 | |
刊名 | microporous and mesoporous materials |
2009-07-01 | |
卷号 | 123期号:1-3页码:306-313 |
关键词 | Fe2O3/SBA-15 Fe/carbon Alkylation reaction chemical vapor infiltration mesoporous carbon |
英文摘要 | fe/sba-15/carbon composites were synthesized by chemical vapor infiltration (cvi) method using ferrocene as concurrent iron and carbon precursor. accordingly, fe2o3 nanoparticles supported on mesoporous sba-15 silica or metallic fe homogeneously embedded in mesoporous carbon were selectively obtained either by oxidizing the carbon component in air or by removing the silica template using an aqueous naoh solution. the fe2o3/sba-15 and fe/carbon composites so obtained were thoroughly characterized by n-2 adsorption/desorption isotherm measurements, powder x-ray diffraction (xrd), transmission electron microscopy and h-2-temperature programmed reduction (h-2-tpr). the effects of cvi duration time and temperature on their corresponding reduction states and particle dispersion, and consequently on their catalytic performances during benzylation reaction of benzene with benzyl chloride were examined and discussed. (c) 2009 elsevier inc. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
关键词[WOS] | containing mesoporous materials ; carbon molecular-sieves ; benzyl-chloride ; iron-oxide ; nanoporous carbon ; pore volume ; nanoparticles ; nanotubes ; silica ; oxidation |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000267099000038 |
公开日期 | 2015-11-17 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/141310] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Liaoning Normal Univ, Fac Chem & Chem Engn, Inst Chem Functionalized Mat, Dalian 116029, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan |
推荐引用方式 GB/T 7714 | Lei, Zhibin,Bai, Shiying,Dang, Liqin,et al. Fe2O3/SBA-15 catalyst synthesized by chemical vapor infiltration for Friedel-Crafts alkylation reaction[J]. microporous and mesoporous materials,2009,123(1-3):306-313. |
APA | Lei, Zhibin.,Bai, Shiying.,Dang, Liqin.,Xia, Haian.,Xu, Qian.,...&Liu, Shang-Bin.(2009).Fe2O3/SBA-15 catalyst synthesized by chemical vapor infiltration for Friedel-Crafts alkylation reaction.microporous and mesoporous materials,123(1-3),306-313. |
MLA | Lei, Zhibin,et al."Fe2O3/SBA-15 catalyst synthesized by chemical vapor infiltration for Friedel-Crafts alkylation reaction".microporous and mesoporous materials 123.1-3(2009):306-313. |
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