Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols

	Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols
	Zhang Xiao-Peng 1,2; Lu Shi-Wei 1
刊名	chemical journal of chinese universities-chinese
	2008-06-10
卷号	29 期号:6 页码:1137-1140
关键词	selenium aniline thiol carbonylation thiocarbarnate
英文摘要	in order to develop a new and facile route to the syntheses of thiocarbamates, selenium-mediated carbonylation of aniline with thiols was studied. mediated by selenium, aniline reacted readily with carbon monooxide and thiols to afford thiocarbamates under the conditions of ambient temperature and atmospheric pressure. the results show that the reaction can proceed well to thiocarbamates in high yields with less hindered alkyl thiols. selenium could be easily recovered and recycled.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	carbon-monoxide ; assisted carbonylation ; hydrolysis ; mechanism
收录类别	SCI ; CCR
语种	英语
WOS记录号	WOS:000257176300014
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140838]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China 2.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
推荐引用方式 GB/T 7714	Zhang Xiao-Peng,Lu Shi-Wei. Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols[J]. chemical journal of chinese universities-chinese,2008,29(6):1137-1140.
APA	Zhang Xiao-Peng,&Lu Shi-Wei.(2008).Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols.chemical journal of chinese universities-chinese,29(6),1137-1140.
MLA	Zhang Xiao-Peng,et al."Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols".chemical journal of chinese universities-chinese 29.6(2008):1137-1140.