Synthesis of novel chiral phosphine-triazine ligand derived from alpha-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation
Jia Di Huang1,2; Xiang Ping Hu1; Zhuo Zheng1
刊名chinese chemical letters
2008-03-01
卷号19期号:3页码:261-263
关键词synthesis alpha-phenylethylamine phosphine-triazine ligand Pd-catalyzed allylic alkylation
英文摘要a novel chiral phosphine-triazine ligand was synthesized from chiral alpha-phenylethylamine through a three-step procedure. in a model reaction of pd-catalyzed allylic alkylation of rac-1,3-diphenylprop-2-en-1-yl pivalate with dimethyl malonate, good enantioselectivity (90% e.e.) was obtained by using this ligand. (c) 2007 zhuo zheng. published by elsevier b.v. on behalf of chinese chemical society. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, multidisciplinary
研究领域[WOS]chemistry
关键词[WOS]substitution-reactions ; hydroboration ; p,n-ligand
收录类别SCI
语种英语
WOS记录号WOS:000256867500004
公开日期2015-11-17
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/140766]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Jia Di Huang,Xiang Ping Hu,Zhuo Zheng. Synthesis of novel chiral phosphine-triazine ligand derived from alpha-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation[J]. chinese chemical letters,2008,19(3):261-263.
APA Jia Di Huang,Xiang Ping Hu,&Zhuo Zheng.(2008).Synthesis of novel chiral phosphine-triazine ligand derived from alpha-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation.chinese chemical letters,19(3),261-263.
MLA Jia Di Huang,et al."Synthesis of novel chiral phosphine-triazine ligand derived from alpha-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation".chinese chemical letters 19.3(2008):261-263.
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