Azadithiolates cofactor of the iron-only hydrogenase and its PR3-monosubstituted derivatives: Synthesis, structure, electrochemistry and protonation

	Azadithiolates cofactor of the iron-only hydrogenase and its PR3-monosubstituted derivatives: Synthesis, structure, electrochemistry and protonation
	Wang, Zhen 1; Liu, Jian-Hui 1; He, Cheng-Jiang 1; Jiang, Shi 1; Akermark, Bjorn 2; Sun, Li-Cheng 1,3
刊名	journal of organometallic chemistry
	2007-11-15
卷号	692 期号:24 页码:5501-5507
关键词	azapropanedithiolate phosphine ligand exchange iron-only hydrogenase
英文摘要	the core structure (mu-sch2)(2)nh[fe-2(co)(6)](5) of fe-only hydrogenases active site model has been synthesized by the condensation of iron carbonyl sulfides, formaldehyde and silyl protected amine. its monosubstituted complexes (mu-sch2)(2)nh[fe-2(co)(5)pr3] (r = ph (6), me (7)) were accordingly prepared. the coordination configurations of 5 and 6 were characterized by x-ray crystallography. protonation of complex 7 to form the n-protonated product occurs in an acetonitrile solution upon addition of triflic acid. the redox properties of these model complexes were studied by cyclic voltammetry. (c) 2007 elsevier b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, inorganic & nuclear ; chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	metal-carbonyl derivatives ; active-site ; model complexes ; tertiary ; coordination ; reduction ; chemistry ; evolution ; cluster ; ligand
收录类别	SCI
语种	英语
WOS记录号	WOS:000253488400023
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140718]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Fine Chem, Dalian 116012, Peoples R China 2.Stockholm Univ, Dept Organ Chem, S-10691 Stockholm, Sweden 3.Royal Inst Technol, KTH Chem Organ Chem, S-10044 Stockholm, Sweden
推荐引用方式 GB/T 7714	Wang, Zhen,Liu, Jian-Hui,He, Cheng-Jiang,et al. Azadithiolates cofactor of the iron-only hydrogenase and its PR3-monosubstituted derivatives: Synthesis, structure, electrochemistry and protonation[J]. journal of organometallic chemistry,2007,692(24):5501-5507.
APA	Wang, Zhen,Liu, Jian-Hui,He, Cheng-Jiang,Jiang, Shi,Akermark, Bjorn,&Sun, Li-Cheng.(2007).Azadithiolates cofactor of the iron-only hydrogenase and its PR3-monosubstituted derivatives: Synthesis, structure, electrochemistry and protonation.journal of organometallic chemistry,692(24),5501-5507.
MLA	Wang, Zhen,et al."Azadithiolates cofactor of the iron-only hydrogenase and its PR3-monosubstituted derivatives: Synthesis, structure, electrochemistry and protonation".journal of organometallic chemistry 692.24(2007):5501-5507.