Synthesis of chiral imidazolinium carbene from a carbohydrate and its rhodium(I) complex

	Synthesis of chiral imidazolinium carbene from a carbohydrate and its rhodium(I) complex
	Shi, Ji-cheng ; Lei, Ni ; Tong, Qingsong ; Peng, Yiru ; Wei, Junfa ; Jia, Li
刊名	european journal of inorganic chemistry
	2007-05-01
期号	15 页码:2221-2224
关键词	nitrogen heterocycles carbenes rhodium carbohydrates chirality
英文摘要	a chiral imidazolinium salt with two bulky carbohydrate subunits, n,n'-1,3-bis(methyl 4,6-0-benzylidene-3-deoxy-alpha-d-altropyrano-3-yl)imidazolinium chloride (4), was synthesized in high yield. deprotonation of 4 with sodium tert-butoxide in the presence of [rhcl(cod)](2) produced nhc-coordinated rhodium complex 5 along with water adduct 6 to a lesser extent depending on the moisture content of the reaction mixture. these compounds were fully characterized by ir, ms, and (1)h and (13)c{(1)h) nmr spectroscopy. ((c) wiley-vch verlag gmbh & co. kgaa, 69451 weinheim, germany, 2007)
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, inorganic & nuclear
研究领域[WOS]	chemistry
关键词[WOS]	n-heterocyclic carbenes ; olefin metathesis catalysts ; phosphine-ligands ; spectroscopic properties ; palladium(ii) complexes ; platinum(ii) complexes ; homogeneous catalysis ; gold(i) complexes ; metal-complexes ; aryl bromides
收录类别	SCI ; IC
语种	英语
WOS记录号	WOS:000246856900014
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140708]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China 2.Shaanxi Normal Univ, Dept Chem, Xian 710062, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Shi, Ji-cheng,Lei, Ni,Tong, Qingsong,et al. Synthesis of chiral imidazolinium carbene from a carbohydrate and its rhodium(I) complex[J]. european journal of inorganic chemistry,2007(15):2221-2224.
APA	Shi, Ji-cheng,Lei, Ni,Tong, Qingsong,Peng, Yiru,Wei, Junfa,&Jia, Li.(2007).Synthesis of chiral imidazolinium carbene from a carbohydrate and its rhodium(I) complex.european journal of inorganic chemistry(15),2221-2224.
MLA	Shi, Ji-cheng,et al."Synthesis of chiral imidazolinium carbene from a carbohydrate and its rhodium(I) complex".european journal of inorganic chemistry .15(2007):2221-2224.