Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy | |
Huang, Jiangou; Lin, Jung Lee; Tzeng, Wen Bih | |
刊名 | spectrochimica acta part a-molecular and biomolecular spectroscopy
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2007-07-01 | |
卷号 | 67期号:3-4页码:989-994 |
关键词 | cresol rotamer cation spectra multiphoton ionization threshold ionization |
英文摘要 | we have applied two-color resonant two-photon mass-analyzed threshold ionization technique to record the vibrational spectra of the selected rotamers of m-cresol. the adiabatic ionization energies of cis and trans m-cresol are determined to be 66,933 +/- 5 and 67,084 +/- 5 cm(-1), respectively. frequencies of the in-plane ring vibrations 6a, 1, and 9b are measured to be 528, 720, 1167 cm(-1) for the cis and 520, 698, and 1153 cm(-1) for the trans m-cresol cation. this indicates that different orientation of the oh group with respect to the ch3 group slightly influences these ring vibrations. (c) 2006 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; technology |
类目[WOS] | spectroscopy |
研究领域[WOS] | spectroscopy |
关键词[WOS] | rotational isomers ; electronic-spectra ; vibrational levels ; supersonic jet ; energy ; s-1 ; fluoroaniline ; potentials ; excitation ; complexes |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000247452400064 |
公开日期 | 2015-11-17 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/140691] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Huang, Jiangou,Lin, Jung Lee,Tzeng, Wen Bih. Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy[J]. spectrochimica acta part a-molecular and biomolecular spectroscopy,2007,67(3-4):989-994. |
APA | Huang, Jiangou,Lin, Jung Lee,&Tzeng, Wen Bih.(2007).Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy.spectrochimica acta part a-molecular and biomolecular spectroscopy,67(3-4),989-994. |
MLA | Huang, Jiangou,et al."Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy".spectrochimica acta part a-molecular and biomolecular spectroscopy 67.3-4(2007):989-994. |
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