Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy

	Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy
	Huang, Jiangou ; Lin, Jung Lee ; Tzeng, Wen Bih
刊名	spectrochimica acta part a-molecular and biomolecular spectroscopy
	2007-07-01
卷号	67 期号:3-4 页码:989-994
关键词	cresol rotamer cation spectra multiphoton ionization threshold ionization
英文摘要	we have applied two-color resonant two-photon mass-analyzed threshold ionization technique to record the vibrational spectra of the selected rotamers of m-cresol. the adiabatic ionization energies of cis and trans m-cresol are determined to be 66,933 +/- 5 and 67,084 +/- 5 cm(-1), respectively. frequencies of the in-plane ring vibrations 6a, 1, and 9b are measured to be 528, 720, 1167 cm(-1) for the cis and 520, 698, and 1153 cm(-1) for the trans m-cresol cation. this indicates that different orientation of the oh group with respect to the ch3 group slightly influences these ring vibrations. (c) 2006 elsevier b.v. all rights reserved.
WOS标题词	science & technology ; technology
类目[WOS]	spectroscopy
研究领域[WOS]	spectroscopy
关键词[WOS]	rotational isomers ; electronic-spectra ; vibrational levels ; supersonic jet ; energy ; s-1 ; fluoroaniline ; potentials ; excitation ; complexes
收录类别	SCI
语种	英语
WOS记录号	WOS:000247452400064
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140691]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Huang, Jiangou,Lin, Jung Lee,Tzeng, Wen Bih. Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy[J]. spectrochimica acta part a-molecular and biomolecular spectroscopy,2007,67(3-4):989-994.
APA	Huang, Jiangou,Lin, Jung Lee,&Tzeng, Wen Bih.(2007).Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy.spectrochimica acta part a-molecular and biomolecular spectroscopy,67(3-4),989-994.
MLA	Huang, Jiangou,et al."Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy".spectrochimica acta part a-molecular and biomolecular spectroscopy 67.3-4(2007):989-994.