Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition

	Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition
	Sun Qi 1; Gu Yuezhu 1; Guo Jingzhong 1; Ying Yongjia 1; Li Xuechu 2; Shen Guanlin 2
刊名	acta physico-chimica sinica
	1995
卷号	11 期号:1 页码:31-37
关键词	Metastable atom Dissociative excitation Vibrational distribution Reaction channel
英文摘要	dissociative excitation of so2,socl2 through single collision with ar(p-3(0,2)) have been studied by observing so(a - x) emission in the beam apparatus. the nascent vibrational distribution of so(a,v') was determined. a surprisal analysis of the nascent vibrational distribution of so(a) indicated that the precursor molecules dissociation could occur predominately from superexcited states (rydberg-states). the formation rate constants of so(a) have been determined for ar(p-3(0,2))/so2 and ar(p-3(0,2))/socl2 reactions, they are: 4.55x10(-12)cm(3)-molcule(-1).s(-1) and 2.87x10(-12)cm(3).molecule(-1).s(-1), respectively. a comparison between the observed formation rate constants and known total quenching rate constants indicated that dissociative excitation processes are minor exit channels.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
收录类别	SCI
语种	英语
WOS记录号	WOS:000207590000007
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140655]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China 2.CAS, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Sun Qi,Gu Yuezhu,Guo Jingzhong,et al. Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition[J]. acta physico-chimica sinica,1995,11(1):31-37.
APA	Sun Qi,Gu Yuezhu,Guo Jingzhong,Ying Yongjia,Li Xuechu,&Shen Guanlin.(1995).Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition.acta physico-chimica sinica,11(1),31-37.
MLA	Sun Qi,et al."Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition".acta physico-chimica sinica 11.1(1995):31-37.