Structure and electrical conductivity of a novel inorganic solid electrolyte: Na-14.5[Al(PO4)(2)F-2](2.5)[Ti(PO4)(2)F-2](0.5) (NATP)

	Structure and electrical conductivity of a novel inorganic solid electrolyte: Na-14.5[Al(PO4)(2)F-2](2.5)[Ti(PO4)(2)F-2](0.5) (NATP)
	Zhang, Ying; Tian, Peng; Sun, Zhengang; Liu, Ziyu; Zhang, Yangyang; Qu, Lihong; Sang, Shiyun; Liu, Zhongmin
刊名	solid state communications
	2007-02-01
卷号	141 期号:7 页码:407-411
关键词	inorganic solid electrolyte NATP hydrothermal synthesis crystalline structure
英文摘要	a novel inorganic solid electrolyte with a layered framework structure stable up to 1043 k, na-14.5[al(po4)(2)f-2](2.5)[ti(po4)(2)f-2](0.5)(natp), has been hydrothermally prepared and characterized by single-crystal and powder x-ray diffraction techniques, x-ray fluorescence (xpf) analysis, ir spectroscopic measurement, thermogravimetric and differential thermal analysis (tga and dta). natp crystallizes in the acentric hexagonal space group p3 with a = 10.448(2), b = 10.448(2), c = 6.589(3) angstrom, z = 1, containing a large number of na+ cations in the interlamellar space and the cavities of its framework. there are six different crystallographic na+ cationic sites, in which 8% na(5) and 12% na(6) sites are vacant. electrical conductivity measurements show that na+ cations exhibit a high mobility with two domains for the electrical conductivity versus temperature. (c) 2006 elsevier ltd. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	physics, condensed matter
研究领域[WOS]	physics
关键词[WOS]	ionic-conductivity ; crystal-structure ; conductors ; separation ; framework ; phosphate
收录类别	SCI
语种	英语
WOS记录号	WOS:000244423600011
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140643]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Appl Catalysis Lab, Dalian Inst Chem Phys, Dalian, Liaoning Prov, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Ying,Tian, Peng,Sun, Zhengang,et al. Structure and electrical conductivity of a novel inorganic solid electrolyte: Na-14.5[Al(PO4)(2)F-2](2.5)[Ti(PO4)(2)F-2](0.5) (NATP)[J]. solid state communications,2007,141(7):407-411.
APA	Zhang, Ying.,Tian, Peng.,Sun, Zhengang.,Liu, Ziyu.,Zhang, Yangyang.,...&Liu, Zhongmin.(2007).Structure and electrical conductivity of a novel inorganic solid electrolyte: Na-14.5[Al(PO4)(2)F-2](2.5)[Ti(PO4)(2)F-2](0.5) (NATP).solid state communications,141(7),407-411.
MLA	Zhang, Ying,et al."Structure and electrical conductivity of a novel inorganic solid electrolyte: Na-14.5[Al(PO4)(2)F-2](2.5)[Ti(PO4)(2)F-2](0.5) (NATP)".solid state communications 141.7(2007):407-411.