Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel

	Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel
	Wei, Qiang; Sun, Ju-Long; Yue, Xian-Fang; Yin, Hong-Ming; Han, Ke-Li
刊名	chemical physics letters
	2007-11-05
卷号	448 期号:1-3 页码:11-15
英文摘要	the photodissociation dynamics of benzoic acid monomer at 266 nm is investigated by probing the nascent oh photoproduct using the laser-induced-fluorescence (lif) technique. the nascent oh radical is distributed in the ground vibrational state and the rotational temperature is 620 +/- 30 k. the f, ((2)pi(3/2)) and f-2 ((2)pi(1/2)) spin-orbit states of oh photofragment are unstatistically populated, and lambda-doublet levels are not equally populated. the present study associated with the available dynamics information predicts that oh radical is mainly produced from benzoic acid monomer on the t-2 energy surface. (c) 2007 elsevier b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical ; physics, atomic, molecular & chemical
研究领域[WOS]	chemistry ; physics
关键词[WOS]	acetic-acid ; state distributions ; absorption-spectrum ; acrylic-acid ; s-2 state ; dissociation ; transitions ; ch3ono ; jet
收录类别	SCI
语种	英语
WOS记录号	WOS:000251230000004
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140466]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Wei, Qiang,Sun, Ju-Long,Yue, Xian-Fang,et al. Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel[J]. chemical physics letters,2007,448(1-3):11-15.
APA	Wei, Qiang,Sun, Ju-Long,Yue, Xian-Fang,Yin, Hong-Ming,&Han, Ke-Li.(2007).Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel.chemical physics letters,448(1-3),11-15.
MLA	Wei, Qiang,et al."Photodissociation dynamics of benzoic acid monomer at 266 nm: The OH product channel".chemical physics letters 448.1-3(2007):11-15.