Theoretical study of stereodynamics for the reaction S(D-1)+D-2

	Theoretical study of stereodynamics for the reaction S(D-1)+D-2
	Zhang Zhi-Hong ; Chen Mao-Du ; Cong Shu-Lin ; Han Ke-Li
刊名	acta physico-chimica sinica
	2006-05-01
卷号	22 期号:5 页码:557-560
关键词	stereodynamics long-lived complex polarization-dependent differential cross section polarization parameter
英文摘要	stereodynamics for the s(d-1)+d-2 reaction have been studied at a collision energy of 22.18 kj.mol(-1) on an ab initio potential energy surface by using time-independent quantum reactive scattering theory. the calculated differential cross sections show forward/backward peaking with weakly asymmetry, which is in agreement with the quasiclassical and experimental results. the state-resolved polarization-dependent differential cross sections and polarization parameters show that the product polarization tends toward a less anisotropic distribution, which indicates existence of a long-lived complex during the reaction because of the existence of deep well on the potential energy surface.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	initio potential surface ; reaction dynamics ; d-2 ; hd ; polarization ; scattering ; state
收录类别	SCI
语种	英语
WOS记录号	WOS:000237709200009
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140337]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Dalian Univ Technol, Dept Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhang Zhi-Hong,Chen Mao-Du,Cong Shu-Lin,et al. Theoretical study of stereodynamics for the reaction S(D-1)+D-2[J]. acta physico-chimica sinica,2006,22(5):557-560.
APA	Zhang Zhi-Hong,Chen Mao-Du,Cong Shu-Lin,&Han Ke-Li.(2006).Theoretical study of stereodynamics for the reaction S(D-1)+D-2.acta physico-chimica sinica,22(5),557-560.
MLA	Zhang Zhi-Hong,et al."Theoretical study of stereodynamics for the reaction S(D-1)+D-2".acta physico-chimica sinica 22.5(2006):557-560.