Unsymmetric-1,3-disubstituted imidazolium salt for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of aryl bromides | |
Yu, HW; Shi, JC; Zhang, H; Yang, PY; Wang, XP; Jin, ZL | |
刊名 | journal of molecular catalysis a-chemical |
2006-05-02 | |
卷号 | 250期号:1-2页码:15-19 |
关键词 | palladium imidazol-2-ylidene Suzuki-Miyaura reaction aryl bromides catalysis |
英文摘要 | a series of 1-(ferrocenylethyl)-3-substituted-imidazolium salts [3-substitute=2,6-di(iso-propyl)phenyl (1a), 2,4,6-trimethylphenyl (1b), tertbutyl (1c), i-ad (1d), cyclohexyl (1e)] have been synthesized from a racemic ferrocertylethyl acetate and the corresponding n-substituted imidazole in high yields (70-94%). a combination of pd(oac)(2) and 1a-d was found to form an excellent catalyst system for the suzuki-miyaura cross-coupling reactions of aryl bromides with phenylboronic acid in the presence of cs2co3 (c) 2006 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | heterocyclic carbene ligands ; room-temperature ; chlorides ; complexes ; amination ; biaryls |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000237318000004 |
公开日期 | 2015-11-17 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/140237] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China |
推荐引用方式 GB/T 7714 | Yu, HW,Shi, JC,Zhang, H,et al. Unsymmetric-1,3-disubstituted imidazolium salt for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of aryl bromides[J]. journal of molecular catalysis a-chemical,2006,250(1-2):15-19. |
APA | Yu, HW,Shi, JC,Zhang, H,Yang, PY,Wang, XP,&Jin, ZL.(2006).Unsymmetric-1,3-disubstituted imidazolium salt for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of aryl bromides.journal of molecular catalysis a-chemical,250(1-2),15-19. |
MLA | Yu, HW,et al."Unsymmetric-1,3-disubstituted imidazolium salt for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of aryl bromides".journal of molecular catalysis a-chemical 250.1-2(2006):15-19. |
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