H-2/N-2 gaseous mixture separation in dense Pd/alpha-Al2O3 hollow fiber membranes: Experimental and simulation studies | |
Wang, W. P.; Thomas, S.; Zhang, X. L.; Pan, X. L.; Yang, W. S.; Xiong, G. X. | |
刊名 | separation and purification technology
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2006-11-01 | |
卷号 | 52期号:1页码:177-185 |
关键词 | alpha-Al2O3 hollow fiber Pd composite membrane H-2/N-2 gaseous mixture hydrogen separation |
英文摘要 | thin pd/alpha-al2o3 hollow fiber (hf) membranes were prepared by an improved electroless plating technique. pure gas permeation experiments showed that the membranes were defect free and had high hydrogen permeance. feeding an equimolar mixture of h-2/n-2, the total diffusion flow rate of hydrogen through the composite membranes was measured in dependence of the total feed flow rate at the inlet of the shell/retentate chamber, of the temperature and of the total trans-membrane pressure difference. furthermore, a mathematical model was derived to describe the hydrogen diffusion in pure and mixture gas experiments. the pure gas experiments were used to determine the membrane parameters. applying the adapted model parameters, the fluxes of hydrogen occurring in the mixture gas experiments were simulated. the comparison between experimental and calculated data showed a very good agreement in a broad parameter range. (c) 2006 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; technology |
类目[WOS] | engineering, chemical |
研究领域[WOS] | engineering |
关键词[WOS] | palladium composite membranes ; fuel-cell applications ; cox-free hydrogen ; catalytic ammonia decomposition ; alloy membranes ; mass-transfer ; permeation ; gas ; reactors ; behavior |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000242285000022 |
公开日期 | 2015-11-17 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/140112] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Inst Catalysis & Petrochem, Madrid 28049, Spain |
推荐引用方式 GB/T 7714 | Wang, W. P.,Thomas, S.,Zhang, X. L.,et al. H-2/N-2 gaseous mixture separation in dense Pd/alpha-Al2O3 hollow fiber membranes: Experimental and simulation studies[J]. separation and purification technology,2006,52(1):177-185. |
APA | Wang, W. P.,Thomas, S.,Zhang, X. L.,Pan, X. L.,Yang, W. S.,&Xiong, G. X..(2006).H-2/N-2 gaseous mixture separation in dense Pd/alpha-Al2O3 hollow fiber membranes: Experimental and simulation studies.separation and purification technology,52(1),177-185. |
MLA | Wang, W. P.,et al."H-2/N-2 gaseous mixture separation in dense Pd/alpha-Al2O3 hollow fiber membranes: Experimental and simulation studies".separation and purification technology 52.1(2006):177-185. |
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