Ethylene polymerization with homogeneous and heterogeneous catalysts based on bis(4-fluorophenyl) methyl-substituted bis(imino)pyridyliron complexes

	Ethylene polymerization with homogeneous and heterogeneous catalysts based on bis(4-fluorophenyl) methyl-substituted bis(imino)pyridyliron complexes
	Semikolenova, Nina V.1; Zhang, Wenjuan 2; Zakharov, Vladimir A.1,3; Bryliakov, Konstantin P.1,3; Sun, Wen-Hua2
刊名	JOURNAL OF APPLIED POLYMER SCIENCE
	2015-11-10
卷号	132 期号:42
关键词	catalysts kinetics morphology polyolefins synthesis and processing
英文摘要	A series of bis(4-fluorophenyl) methyl-substituted bis(imino)pyridyliron chloride complexes were immobilized on oxide supports. The kinetics of ethylene polymerization by both homogeneous and heterogeneous systems was followed, the catalysts mostly demonstrating high activities. The effect of the ligands nature and reaction conditions on the catalytic activities and molecular weights of the resultant polyethylenes was examined. In contrast to homogeneous systems, the supported iron complexes were found to exhibit high and stable activity upon activation with triisobutyl aluminium, producing high-molecular-weight polyethylene with good morphology. (C) 2015 Wiley Periodicals, Inc.
收录类别	SCI
语种	英语
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/28891]
专题	化学研究所_工程塑料实验室
作者单位	1.Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia 2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 3.Novosibirsk State Univ, Novosibirsk 630090, Russia
推荐引用方式 GB/T 7714	Semikolenova, Nina V.,Zhang, Wenjuan,Zakharov, Vladimir A.,et al. Ethylene polymerization with homogeneous and heterogeneous catalysts based on bis(4-fluorophenyl) methyl-substituted bis(imino)pyridyliron complexes[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2015,132(42).
APA	Semikolenova, Nina V.,Zhang, Wenjuan,Zakharov, Vladimir A.,Bryliakov, Konstantin P.,&Sun, Wen-Hua.(2015).Ethylene polymerization with homogeneous and heterogeneous catalysts based on bis(4-fluorophenyl) methyl-substituted bis(imino)pyridyliron complexes.JOURNAL OF APPLIED POLYMER SCIENCE,132(42).
MLA	Semikolenova, Nina V.,et al."Ethylene polymerization with homogeneous and heterogeneous catalysts based on bis(4-fluorophenyl) methyl-substituted bis(imino)pyridyliron complexes".JOURNAL OF APPLIED POLYMER SCIENCE 132.42(2015).