Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor | |
Cai, R; Song, SQ; Ji, BF; Yang, WS; Sun, GQ; Xin, Q | |
刊名 | catalysis today
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2005-06-30 | |
卷号 | 104期号:2-4页码:200-204 |
关键词 | phenol oxidation membrane reactor PEMFC electrochemical |
英文摘要 | in the present work, direct hydroxylation of benzene to phenol by using in situ generated h2o2 with electricity cogeneration was carried out in a proton exchange membrane fuel cell (pemfc) reactor. phenol was produced only when there was current through the external circuit. no other organic products were detected during this electrochemical process. a rotating ring-disc electrode (rrde) technique was used to quantitatively detect the intermediate h2o2 in an acid electrolyte solution at different potentials and temperatures. the rrde studies showed that the in situ generated h2o2 may play a crucial role during the formation of phenol. the formation rate of phenol could be controlled by adjusting the current or cell potential. (c) 2005 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | fuel-cell system ; oxygen reduction ; oxidation ; benzene ; performance ; electrode |
收录类别 | ISTP ; SCI |
语种 | 英语 |
WOS记录号 | WOS:000230204100014 |
公开日期 | 2015-11-10 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/139928] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Direct Alcohol Fuel Cell Lab, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Cai, R,Song, SQ,Ji, BF,et al. Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor[J]. catalysis today,2005,104(2-4):200-204. |
APA | Cai, R,Song, SQ,Ji, BF,Yang, WS,Sun, GQ,&Xin, Q.(2005).Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor.catalysis today,104(2-4),200-204. |
MLA | Cai, R,et al."Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor".catalysis today 104.2-4(2005):200-204. |
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