Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor

	Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor
	Cai, R ; Song, SQ ; Ji, BF ; Yang, WS ; Sun, GQ ; Xin, Q
刊名	catalysis today
	2005-06-30
卷号	104 期号:2-4 页码:200-204
关键词	phenol oxidation membrane reactor PEMFC electrochemical
英文摘要	in the present work, direct hydroxylation of benzene to phenol by using in situ generated h2o2 with electricity cogeneration was carried out in a proton exchange membrane fuel cell (pemfc) reactor. phenol was produced only when there was current through the external circuit. no other organic products were detected during this electrochemical process. a rotating ring-disc electrode (rrde) technique was used to quantitatively detect the intermediate h2o2 in an acid electrolyte solution at different potentials and temperatures. the rrde studies showed that the in situ generated h2o2 may play a crucial role during the formation of phenol. the formation rate of phenol could be controlled by adjusting the current or cell potential. (c) 2005 elsevier b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, applied ; chemistry, physical ; engineering, chemical
研究领域[WOS]	chemistry ; engineering
关键词[WOS]	fuel-cell system ; oxygen reduction ; oxidation ; benzene ; performance ; electrode
收录类别	ISTP ; SCI
语种	英语
WOS记录号	WOS:000230204100014
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/139928]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Direct Alcohol Fuel Cell Lab, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Cai, R,Song, SQ,Ji, BF,et al. Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor[J]. catalysis today,2005,104(2-4):200-204.
APA	Cai, R,Song, SQ,Ji, BF,Yang, WS,Sun, GQ,&Xin, Q.(2005).Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor.catalysis today,104(2-4),200-204.
MLA	Cai, R,et al."Phenol cogeneration with electricity by using in situ generated H2O2 in a H-2-O2PEMFC reactor".catalysis today 104.2-4(2005):200-204.