Selective hydrogenation of benzene to cyclohexene in a monolithic reactor

	Selective hydrogenation of benzene to cyclohexene in a monolithic reactor
	Zhao, D ; Chen, GW ; Yuan, Q
刊名	chinese journal of catalysis
	2005-09-01
卷号	26 期号:9 页码:824-828
关键词	monolithic catalyst ruthenium zirconia benzene hydrogenation cyclohexene
英文摘要	an attractive field of industrial use of a monolithic reactor lies in multiphase catalytic reactions, especially hydrogenation and oxidation of hydrocarbons, due to its superior interphase mass transfer performance. in this paper, liquid-phase selective hydrogenation of benzene to cyclohexene over a ru/zro2 honeycomb monolithic catalyst was studied in detail. the effects of catalyst and reaction variables, such as the support type, ruthenium content, catalyst pretreatment, addition of water or salt in reactants, reaction temperature, hydrogen pressure and volume ratio of water to benzene, on the performance of the reaction were investigated. good yields of cyclohexene could be obtained using ruthenium particles supported on hydrophilic oxides, like silica, alumina, titania and zirconia. it should be noted that the reaction can occur without catalyst prereduction in hydrogen flow in the monolithic reactor. no cyclohexene was detected in the absence of reaction additives such as water or znso4 solution, but the selectivity for cyclohexene dramatically increased to higher than 20 % when these reaction modifiers were added. there existed an optimum volume ratio of water to benzene for high yield of cyclohexene. better results were achieved in the presence of 0.1 mol/l znso4 under the reaction temperatures of 413 similar to 443 k and pressures of 3 - 4 mpa.
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, applied ; chemistry, physical ; engineering, chemical
研究领域[WOS]	chemistry ; engineering
关键词[WOS]	ruthenium catalysts ; kinetics
收录类别	SCI
语种	英语
WOS记录号	WOS:000232474800021
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/139733]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhao, D,Chen, GW,Yuan, Q. Selective hydrogenation of benzene to cyclohexene in a monolithic reactor[J]. chinese journal of catalysis,2005,26(9):824-828.
APA	Zhao, D,Chen, GW,&Yuan, Q.(2005).Selective hydrogenation of benzene to cyclohexene in a monolithic reactor.chinese journal of catalysis,26(9),824-828.
MLA	Zhao, D,et al."Selective hydrogenation of benzene to cyclohexene in a monolithic reactor".chinese journal of catalysis 26.9(2005):824-828.