ROLE OF CARRIERS IN THE SELECTIVE HYDROGENATION OF CYCLOPENTADIENE OVER SUPPORTED PALLADIUM CATALYSIS

	ROLE OF CARRIERS IN THE SELECTIVE HYDROGENATION OF CYCLOPENTADIENE OVER SUPPORTED PALLADIUM CATALYSIS
	Zhang Shulin; Xu Jun; Liao Shijian; Yu Daorong; Zhang Yiping
刊名	acta physico-chimica sinica
	1989
卷号	5 期号:1 页码:38-43
英文摘要	several supported palladium catalysts were prepared and thier effects on the kinetic behaviors in the selective hydrogenation of cyclopentadiene were studied. experiments show that cyclopentadiene inhibits the hydrogenation of cyclopentene. data based on kinetic analysis indicate that the coordination of cyclopentadiene is much stronger than that of cyclopentene which should be the main factor of this inhibition reaction. catalyst carriers via thier ligand effects can influence the ratio of the coordination equilibrium constants k-d/k-e and the rate constants k-2/k-4, which in turn change the selectivities and activities of catalyets.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
收录类别	SCI
语种	英语
WOS记录号	WOS:000207572000009
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/139488]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Acad Sinica, Dalian Inst Chem Phys, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Zhang Shulin,Xu Jun,Liao Shijian,et al. ROLE OF CARRIERS IN THE SELECTIVE HYDROGENATION OF CYCLOPENTADIENE OVER SUPPORTED PALLADIUM CATALYSIS[J]. acta physico-chimica sinica,1989,5(1):38-43.
APA	Zhang Shulin,Xu Jun,Liao Shijian,Yu Daorong,&Zhang Yiping.(1989).ROLE OF CARRIERS IN THE SELECTIVE HYDROGENATION OF CYCLOPENTADIENE OVER SUPPORTED PALLADIUM CATALYSIS.acta physico-chimica sinica,5(1),38-43.
MLA	Zhang Shulin,et al."ROLE OF CARRIERS IN THE SELECTIVE HYDROGENATION OF CYCLOPENTADIENE OVER SUPPORTED PALLADIUM CATALYSIS".acta physico-chimica sinica 5.1(1989):38-43.