Applications of in situ NMR in catalytic processes of organic reactions

	Applications of in situ NMR in catalytic processes of organic reactions
	Han, XW; Yan, ZM; Zhang, WP; Bao, XH
刊名	current organic chemistry
	2001-10-01
卷号	5 期号:10 页码:1017-1037
英文摘要	in situ mas nmr has been demonstrated to be a superior technique for analyzing desorbed reactants, reacting adsorbates, intermediates and products. the results are useful for getting deeper insights into catalytic processes and reaction kinetics, and for revealing the mechanisms of organic reactions. the utility of in situ nmr spectroscopy has demonstrated that this technique is an important means for the studies of catalytic organic reactions. the objective of this paper is to give a review on the generation of apparatus for in situ mas nmr experiments, and to illustrate the applications of the in situ mas nmr techniques in various important organic reactions catalyzed by solid catalysts. the typical reactions studied by in situ mas nmr techniques include conversion of methanol to hydrocarbons (mtg process), aromatization of methane, ethylbenzene reaction over zeolite hmor. observation of carbenium intermediates formation, and photocatalytic organic reaction.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	solid-state nmr ; angle-spinning nmr ; methane dehydro-aromatization ; molecular-sieve catalysts ; to-hydrocarbon chemistry ; carbon carbon bond ; pt-hmor catalysts ; o-xylene mixture ; in-situ ; mas nmr
收录类别	SCI
语种	英语
WOS记录号	WOS:000172120000004
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/138848]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Han, XW,Yan, ZM,Zhang, WP,et al. Applications of in situ NMR in catalytic processes of organic reactions[J]. current organic chemistry,2001,5(10):1017-1037.
APA	Han, XW,Yan, ZM,Zhang, WP,&Bao, XH.(2001).Applications of in situ NMR in catalytic processes of organic reactions.current organic chemistry,5(10),1017-1037.
MLA	Han, XW,et al."Applications of in situ NMR in catalytic processes of organic reactions".current organic chemistry 5.10(2001):1017-1037.