Applications of in situ NMR in catalytic processes of organic reactions | |
Han, XW; Yan, ZM; Zhang, WP; Bao, XH | |
刊名 | current organic chemistry
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2001-10-01 | |
卷号 | 5期号:10页码:1017-1037 |
英文摘要 | in situ mas nmr has been demonstrated to be a superior technique for analyzing desorbed reactants, reacting adsorbates, intermediates and products. the results are useful for getting deeper insights into catalytic processes and reaction kinetics, and for revealing the mechanisms of organic reactions. the utility of in situ nmr spectroscopy has demonstrated that this technique is an important means for the studies of catalytic organic reactions. the objective of this paper is to give a review on the generation of apparatus for in situ mas nmr experiments, and to illustrate the applications of the in situ mas nmr techniques in various important organic reactions catalyzed by solid catalysts. the typical reactions studied by in situ mas nmr techniques include conversion of methanol to hydrocarbons (mtg process), aromatization of methane, ethylbenzene reaction over zeolite hmor. observation of carbenium intermediates formation, and photocatalytic organic reaction. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, organic |
研究领域[WOS] | chemistry |
关键词[WOS] | solid-state nmr ; angle-spinning nmr ; methane dehydro-aromatization ; molecular-sieve catalysts ; to-hydrocarbon chemistry ; carbon carbon bond ; pt-hmor catalysts ; o-xylene mixture ; in-situ ; mas nmr |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000172120000004 |
公开日期 | 2015-11-10 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/138848] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China |
推荐引用方式 GB/T 7714 | Han, XW,Yan, ZM,Zhang, WP,et al. Applications of in situ NMR in catalytic processes of organic reactions[J]. current organic chemistry,2001,5(10):1017-1037. |
APA | Han, XW,Yan, ZM,Zhang, WP,&Bao, XH.(2001).Applications of in situ NMR in catalytic processes of organic reactions.current organic chemistry,5(10),1017-1037. |
MLA | Han, XW,et al."Applications of in situ NMR in catalytic processes of organic reactions".current organic chemistry 5.10(2001):1017-1037. |
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