Molecule imprinting chiral stationary phase

	Molecule imprinting chiral stationary phase
	Meng, ZH; Zhou, LM; Wang, JF; Wang, QH; Zhu, DQ
刊名	biomedical chromatography
	1999-10-01
卷号	13 期号:6 页码:389-393
英文摘要	molecule imprinting polymers (mips) with high chiral selectivity for n-alpha-protected amino acids were synthesized in polar solvent using acrylamide (am) or combined functional monomer methacrylic acid (maa) + vinyl pyridine (vp). factors that influence the chiral selectivity of mips and mechanisms of the chiral recognition process were investigated. it was found that the rigid structure and the polar functional group of the print molecule were very important for the chiral selectivity of mips. for mips made using a combined functional monomer, ionic and hydrophobic interaction may be responsible for the chiral recognition process in aqeous media. the number of binding sites on mips and dissociation constants for the complex of enantiomers and mips were determined by frontal chromatography analysis. copyright (c) 1999 john wiley & sons, ltd.
WOS标题词	science & technology ; life sciences & biomedicine ; physical sciences
类目[WOS]	biochemical research methods ; biochemistry & molecular biology ; chemistry, analytical ; pharmacology & pharmacy
研究领域[WOS]	biochemistry & molecular biology ; chemistry ; pharmacology & pharmacy
关键词[WOS]	resolution
收录类别	SCI
语种	英语
WOS记录号	WOS:000082935900003
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/138577]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China
推荐引用方式 GB/T 7714	Meng, ZH,Zhou, LM,Wang, JF,et al. Molecule imprinting chiral stationary phase[J]. biomedical chromatography,1999,13(6):389-393.
APA	Meng, ZH,Zhou, LM,Wang, JF,Wang, QH,&Zhu, DQ.(1999).Molecule imprinting chiral stationary phase.biomedical chromatography,13(6),389-393.
MLA	Meng, ZH,et al."Molecule imprinting chiral stationary phase".biomedical chromatography 13.6(1999):389-393.