Formation, photodissociation and structures of Si, Ge, Sn, Pb/P binary atomic cluster ions | |
Liu, JB; Han, CY; Zeng, R; Gao, Z; Zhu, QH | |
刊名 | acta physico-chimica sinica
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1999-10-01 | |
卷号 | 15期号:10页码:883-889 |
关键词 | binary atomic clusters laser ablation laser photodissociation TOF mass spectrometer Wade's rule |
英文摘要 | the formation and photodissociation of group hv (si, ge, sn, pb)/p binary cluster ions, produced by laser ablation, were studied with a tandem tof mass spectrometer, the stability of these cluster ions is influenced by their electronic and geometric structures, and the geometric stability becomes more important for heavier group iv /p cluster ions. two types of binary clusters marked with the magic numbers were observed: one type of magic clusters may be explained by the wade's rule, in which p atom either attaches as electron-donating ligand to the close-skeleton of group iv atoms, or joins the close-skeleton directly; another type of magic clusters are isoelectronic with magic species of neutral group iv clusters or p clusters. the possible structures of magic cluster ions were studied by ab initio calculation and the wade's rule. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | group-iv ; phosphorus ; patterns |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000083087800005 |
公开日期 | 2015-11-10 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/138523] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, JB,Han, CY,Zeng, R,et al. Formation, photodissociation and structures of Si, Ge, Sn, Pb/P binary atomic cluster ions[J]. acta physico-chimica sinica,1999,15(10):883-889. |
APA | Liu, JB,Han, CY,Zeng, R,Gao, Z,&Zhu, QH.(1999).Formation, photodissociation and structures of Si, Ge, Sn, Pb/P binary atomic cluster ions.acta physico-chimica sinica,15(10),883-889. |
MLA | Liu, JB,et al."Formation, photodissociation and structures of Si, Ge, Sn, Pb/P binary atomic cluster ions".acta physico-chimica sinica 15.10(1999):883-889. |
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