Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage

	Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage
	Xing, XP; Liu, HT; Tang, ZC
刊名	physchemcomm
	2003-04-22
卷号	6 页码:32-35
英文摘要	this article reports on the generation of [m-m-phenyl](-) (m = mn-cu) complexes, which are very rare cases in chemistry. experimental results showed that the typical cation products for the reactions of all 3d transition metal clusters (sc-cu) with benzene were different [m-m(c6h6)(n)](+) (m = sc-cu) species, while the typical anion products for the late 3d transition metals were [m-m-c6h5](-) (m = mn-cu) complexes. their formation mechanisms, which involve anion metal clusters inducing a selective benzene c - h cleavage in the gas phase, were proposed.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	flight mass-spectrometer ; photoelectron-spectroscopy ; charge-transfer ; photodissociation ; chemisorption
收录类别	SCI
语种	英语
WOS记录号	WOS:000182473600001
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/138372]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Ctr Mol Sci, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Xing, XP,Liu, HT,Tang, ZC. Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage[J]. physchemcomm,2003,6:32-35.
APA	Xing, XP,Liu, HT,&Tang, ZC.(2003).Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage.physchemcomm,6,32-35.
MLA	Xing, XP,et al."Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage".physchemcomm 6(2003):32-35.