Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides

	Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides
	Guerrero-Ruiz, A ; Zhang, Y ; Bachiller-Baeza, B ; Rodriguez-Ramos, I
刊名	catalysis letters
	1998
卷号	55 期号:3-4 页码:165-168
关键词	molybdenum nitride catalysts crotonaldehyde hydrogenation
英文摘要	the gas-phase hydrogenation of crotonaldehyde has been performed over unsupported mo(2)n and over mo(2)n supported on two carbonaceous materials, an activated carbon (ac) and a high surface area graphite (g). these catalysts were in situ prepared by the temperature-programmed reaction of moo(3) and carbon-supported mo precursors with nh(3). it is found that selectivity to the unsaturated alcohol is maximum for the mo(2)n/g sample, where crotylalcohol selectivities exceed the 60% during all time in reaction. higher selectivity surface sites are associated with the (200) planes of the gamma-mo(2)n crystallites.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	alpha,beta-unsaturated aldehydes ; catalysts ; selectivity ; cinnamaldehyde ; platinum ; carbides
收录类别	SCI
语种	英语
WOS记录号	WOS:000077537200006
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/138191]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Univ Nacl Educ Distancia, Fac Ciencias, Dept Quim Inorgan, Madrid 28040, Spain 2.CSIC, Inst Catalisis & Petroleoquim, E-28049 Madrid, Spain 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Guerrero-Ruiz, A,Zhang, Y,Bachiller-Baeza, B,et al. Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides[J]. catalysis letters,1998,55(3-4):165-168.
APA	Guerrero-Ruiz, A,Zhang, Y,Bachiller-Baeza, B,&Rodriguez-Ramos, I.(1998).Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides.catalysis letters,55(3-4),165-168.
MLA	Guerrero-Ruiz, A,et al."Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides".catalysis letters 55.3-4(1998):165-168.