The o-chlorotoluene photodissociation at 266 nm

	The o-chlorotoluene photodissociation at 266 nm
	Deng, WQ; Zhan, JP; Han, KL; He, GZ; Lou, NQ
刊名	science in china series b-chemistry
	1998-10-01
卷号	41 期号:5 页码:471-478
关键词	o-chlorotoluene photodissociation at 266 nm transfer of H atom energy barrier B3LYP ab initio calculation
英文摘要	based on the ab initio calculation results, the hydrogen atom transfer has been investigated. in order to explain the experimental results, a new mechanism is proposed, that is, hydrogen transfer occurs before but not after cl atom eliminates from aromatic ring. the calculation result strongly supports this mechanism.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	photo-dissociation ; internal-rotation ; photofragmentation ; chlorobenzene ; fragment ; glyoxal
收录类别	SCI
语种	英语
WOS记录号	WOS:000076532000004
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/138126]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Deng, WQ,Zhan, JP,Han, KL,et al. The o-chlorotoluene photodissociation at 266 nm[J]. science in china series b-chemistry,1998,41(5):471-478.
APA	Deng, WQ,Zhan, JP,Han, KL,He, GZ,&Lou, NQ.(1998).The o-chlorotoluene photodissociation at 266 nm.science in china series b-chemistry,41(5),471-478.
MLA	Deng, WQ,et al."The o-chlorotoluene photodissociation at 266 nm".science in china series b-chemistry 41.5(1998):471-478.