Synthesis, crystal structure and thermochemistry of nickel hydrogen pyridine-2,6-dicarboxylate

	Synthesis, crystal structure and thermochemistry of nickel hydrogen pyridine-2,6-dicarboxylate
	Zhong, Wen-Wen 1; Di, You-Ying 1; Tan, Zhi-Cheng 2,3; Dou, Jian-Min 1
刊名	thermochimica acta
	2013-05-20
卷号	560 页码:27-33
关键词	Nickel hydrogen pyridine-2 Crystal structure Low-temperature heat capacity Thermodynamic function Standard molar enthalpy of formation 6-dicarboxylate trihydrate
英文摘要	nickel hydrogen pyridine-2,6-dicarboxylate trihydrate (ni(hdpc)(2)center dot 3h(2)o) was synthesized by the method of liquid phase synthesis. the composition and crystal structure of the complex were determined by chemical analysis, elemental analysis, and x-ray crystallography. low-temperature heat capacities of the complex were measured over the temperature range from 78 to 353 k. smoothed molar heat capacities and thermodynamic functions of the complex relative to the standard reference temperature 298.15 k were calculated based on the fitted polynomial equation. a reasonable thermochemical cycle was designed, and the standard molar enthalpies of dissolution for the reactants and products of the synthesis reaction in a selected solvent were measured. eventually, the standard molar enthalpy of formation of the title complex was derived to be -(2467.9 +/- 3.2) kj mol(-1) in accordance with hess's law. (c) 2013 elsevier b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, analytical ; chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	temperature heat-capacities ; standard molar enthalpy ; chloride
收录类别	SCI
语种	英语
WOS记录号	WOS:000319175200005
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/137933]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhong, Wen-Wen,Di, You-Ying,Tan, Zhi-Cheng,et al. Synthesis, crystal structure and thermochemistry of nickel hydrogen pyridine-2,6-dicarboxylate[J]. thermochimica acta,2013,560:27-33.
APA	Zhong, Wen-Wen,Di, You-Ying,Tan, Zhi-Cheng,&Dou, Jian-Min.(2013).Synthesis, crystal structure and thermochemistry of nickel hydrogen pyridine-2,6-dicarboxylate.thermochimica acta,560,27-33.
MLA	Zhong, Wen-Wen,et al."Synthesis, crystal structure and thermochemistry of nickel hydrogen pyridine-2,6-dicarboxylate".thermochimica acta 560(2013):27-33.