Transition-metal mediated carbon-sulfur bond activation and transformations | |
Wang, Liandi1; He, Wei1; Yu, Zhengkun1,2 | |
刊名 | chemical society reviews |
2013 | |
卷号 | 42期号:2页码:599-621 |
英文摘要 | c-s bond activation, cleavage and transformations by means of transition metal compounds have recently become more and more important in the petroleum industry and synthetic chemistry. homogeneous transition metal compounds have been investigated in order to provide the fundamental insight into the c-s bond cleavage in problematic organosulfur compounds such as thiophene, benzo- and dibenzothiophene derivatives. rendering transition-metal mediated reactions with organosulfur compounds catalytic may provide promising routes to deep hydrodesulfurization of petroleum feedstocks, and offer potentially useful synthetic protocols for cross-couplings and biomimetic organic synthesis. during the last few decades increasing work was documented on c-s bond activation and transformations by means of transition metal compounds. this review summarizes the recent advances in c-s bond cleavage via the insertion of transition metals into the inert c-s bonds of these problematic organosulfur compounds, and transition-metal mediated c-s bond transformations via c-s activation through cross-couplings of thioesters, ketene dithioacetals, sulfonyl chlorides, and other diverse organosulfur compounds. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | c-s bond ; palladium-catalyzed thiocarbonylation ; highly regioselective thiocarbonylation ; oxo ketene dithioacetals ; cross-coupling reaction ; ray crystal-structure ; hds model systems ; sulfonyl chlorides ; efficient synthesis ; forming reactions |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000312460600012 |
公开日期 | 2015-11-10 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/137790] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Liandi,He, Wei,Yu, Zhengkun. Transition-metal mediated carbon-sulfur bond activation and transformations[J]. chemical society reviews,2013,42(2):599-621. |
APA | Wang, Liandi,He, Wei,&Yu, Zhengkun.(2013).Transition-metal mediated carbon-sulfur bond activation and transformations.chemical society reviews,42(2),599-621. |
MLA | Wang, Liandi,et al."Transition-metal mediated carbon-sulfur bond activation and transformations".chemical society reviews 42.2(2013):599-621. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论