Nanosized FeOx overlayers on Pt-skin surfaces for low temperature CO oxidation | |
Xu, Hong; Fu, Qiang; Bao, Xinhe | |
刊名 | chinese journal of catalysis
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2013-11-01 | |
卷号 | 34期号:11页码:2029-2035 |
关键词 | CO oxidation Pt-skin Fe oxide Interface catalysis |
英文摘要 | pt-cu/carbon black catalysts were prepared by an impregnation-reduction method followed by acid leaching. the structure and composition of pt-cu nanoparticles treated under different conditions were investigated by inductively coupled plasma atomic emission spectrometry, x-ray diffraction, and x-ray photoelectron spectroscopy. ptcu3 alloy formed upon annealing pt-cu/carbon black catalysts in h-2. acid leaching produced pt-cu nanoparticles consisting of pt-skeleton surface structure and ptcu3 alloy core. the pt-skeleton could be transformed to well-defined pt-skin structure through further annealing the leached pt-cu nanoparticles in h-2. decorating the pt-skin surfaces with fe oxide nanopatches resulted in enhanced reactivity in the preferential oxidation of co in excess h-2. the tri-component pt-cu-fe catalysts exhibited comparable activity to the bi-component pt-fe catalysts but used much less pt. (c) 2013, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | oxygen reduction reaction ; shell nanoparticles ; bimetallic catalysts ; tolerant electrocatalysts ; preferential oxidation ; fept nanoparticles ; ferrous centers ; alloy ; platinum ; hydrogen |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000326769800010 |
公开日期 | 2015-11-10 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/137637] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Hong,Fu, Qiang,Bao, Xinhe. Nanosized FeOx overlayers on Pt-skin surfaces for low temperature CO oxidation[J]. chinese journal of catalysis,2013,34(11):2029-2035. |
APA | Xu, Hong,Fu, Qiang,&Bao, Xinhe.(2013).Nanosized FeOx overlayers on Pt-skin surfaces for low temperature CO oxidation.chinese journal of catalysis,34(11),2029-2035. |
MLA | Xu, Hong,et al."Nanosized FeOx overlayers on Pt-skin surfaces for low temperature CO oxidation".chinese journal of catalysis 34.11(2013):2029-2035. |
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