Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3 center dot 6H(2)O/BF3 center dot(Et)(2)O in ethanol

	Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3 center dot 6H(2)O/BF3 center dot(Et)(2)O in ethanol
	Jia, Xiuquan 1,2; Ma, Jiping 1; Che, Penghua 1,2; Lu, Fang 1; Miao, Hong 1; Gao, Jin 1; Xu, Jie 1
刊名	journal of energy chemistry
	2013
卷号	22 期号:1 页码:93-97
关键词	carbohydrates 5-ethoxymethylfurfural catalysis Lewis acid
英文摘要	direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural (emf) catalyzed by lewis acid in ethanol was investigated. it was found that bf3 center dot(et)(2)o was favorable for 5-hydroxymethylfurfural (hmf) etherification to emf. bf3 center dot(et)(2)o combination with alcl3 center dot 6h(2)o with the molar ratio of 1 was an effective catalyst system for synthesis of emf from fructose-based carbohydrates. 55.0%, 45.4% and 23.9% of emf yields were obtained from fructose, inulin and sucrose under optimized conditions, respectively.
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, applied ; chemistry, physical ; energy & fuels ; engineering, chemical
研究领域[WOS]	chemistry ; energy & fuels ; engineering
关键词[WOS]	lignocellulosic biomass ; cellulose ; derivatives ; chemicals ; 2,5-diformylfuran ; etherification ; alcohol ; biofuel ; glucose ; system
收录类别	SCI
语种	英语
WOS记录号	WOS:000318050700013
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/137536]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Jia, Xiuquan,Ma, Jiping,Che, Penghua,et al. Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3 center dot 6H(2)O/BF3 center dot(Et)(2)O in ethanol[J]. journal of energy chemistry,2013,22(1):93-97.
APA	Jia, Xiuquan.,Ma, Jiping.,Che, Penghua.,Lu, Fang.,Miao, Hong.,...&Xu, Jie.(2013).Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3 center dot 6H(2)O/BF3 center dot(Et)(2)O in ethanol.journal of energy chemistry,22(1),93-97.
MLA	Jia, Xiuquan,et al."Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3 center dot 6H(2)O/BF3 center dot(Et)(2)O in ethanol".journal of energy chemistry 22.1(2013):93-97.