| Thermal Conversion of Methane to Formaldehyde Promoted by Gold in AuNbO3+ Cluster Cations | |
| Wang, Li-Na1; Zhou, Zhen-Xun1; Li, Xiao-Na2; Ma, Tong-Mei1; He, Sheng-Gui2 | |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 2015-04-27 | |
| 卷号 | 21期号:18页码:6957-6961 |
| 关键词 | C1 building blocks cluster compounds density functional calculations gold mass spectrometry |
| 英文摘要 | In addition to generation of a methyl radical, formation of a formaldehyde molecule was observed in the thermal reaction of methane with AuNbO3+ heteronuclear oxide cluster cations. The clusters were prepared by laser ablation and mass-selected to react with CH4 in an ion-trap reactor under thermal collision conditions. The reaction was studied by mass spectrometry and DFT calculations. The latter indicated that the gold atom promotes formaldehyde formation through transformation of an Au-O bond into an Au-Nb bond during the reaction. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-11-03 |
| 内容类型 | 期刊论文 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28650]  |
| 专题 | 化学研究所_分子动态与稳态结构实验室 |
| 作者单位 | 1.S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Li-Na,Zhou, Zhen-Xun,Li, Xiao-Na,et al. Thermal Conversion of Methane to Formaldehyde Promoted by Gold in AuNbO3+ Cluster Cations[J]. CHEMISTRY-A EUROPEAN JOURNAL,2015,21(18):6957-6961. |
| APA | Wang, Li-Na,Zhou, Zhen-Xun,Li, Xiao-Na,Ma, Tong-Mei,&He, Sheng-Gui.(2015).Thermal Conversion of Methane to Formaldehyde Promoted by Gold in AuNbO3+ Cluster Cations.CHEMISTRY-A EUROPEAN JOURNAL,21(18),6957-6961. |
| MLA | Wang, Li-Na,et al."Thermal Conversion of Methane to Formaldehyde Promoted by Gold in AuNbO3+ Cluster Cations".CHEMISTRY-A EUROPEAN JOURNAL 21.18(2015):6957-6961. |
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