Living and Stereoselective Polymerization of Rac-Lactide by Bimetallic Aluminum Schiff-Base Complexes

	Living and Stereoselective Polymerization of Rac-Lactide by Bimetallic Aluminum Schiff-Base Complexes
	Qu, Zhi ; Duan, Ranlong ; Pang, Xuan ; Gao,Bo ; Li,Xiang ; Tang,Zhaohui ; Wang,Xianhong ; Chen,Xuesi
刊名	journal of polymer science part a-polymer chemistry
	2014
卷号	52 期号:9 页码:1344-1352
关键词	RING-OPENING POLYMERIZATION GROUP-3 METAL-COMPLEXES RACEMIC LACTIDE STEREOCOMPLEX FORMATION FERRIC ALKOXIDES INITIATOR MECHANISM KINETICS SALEN STEREOCHEMISTRY
通讯作者	pang,x
英文摘要	a series of bimetallic aluminum schiff-base complexes have been prepared and characterized. the complexes used as catalysts were applied in the lactide polymerization to test their activities and stereoselectivities. all polymerizations are living, as evidenced by the narrow polydispersities and the good fit between calculated and found number-average molecular weights of the isolated polymers. isotactic enriched polylactide was obtained by using these complexes. kinetic studies indicated that the polymerizations are both first-ordered with respect to lactide monomer and catalyst. (c) 2014 wiley periodicals, inc. j. polym. sci., part a: polym. chem. 2014, 52, 1344-1352
收录类别	SCI
语种	英语
公开日期	2015-10-27
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/57366]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Qu, Zhi,Duan, Ranlong,Pang, Xuan,et al. Living and Stereoselective Polymerization of Rac-Lactide by Bimetallic Aluminum Schiff-Base Complexes[J]. journal of polymer science part a-polymer chemistry,2014,52(9):1344-1352.
APA	Qu, Zhi.,Duan, Ranlong.,Pang, Xuan.,Gao,Bo.,Li,Xiang.,...&Chen,Xuesi.(2014).Living and Stereoselective Polymerization of Rac-Lactide by Bimetallic Aluminum Schiff-Base Complexes.journal of polymer science part a-polymer chemistry,52(9),1344-1352.
MLA	Qu, Zhi,et al."Living and Stereoselective Polymerization of Rac-Lactide by Bimetallic Aluminum Schiff-Base Complexes".journal of polymer science part a-polymer chemistry 52.9(2014):1344-1352.